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73724-45-5

Basic Information
CAS No.: 73724-45-5
Name: Fmoc-L-Serine
Article Data: 43
Molecular Structure:
Molecular Structure of 73724-45-5 (Fmoc-L-Serine)
Formula: C18H17NO5
Molecular Weight: 327.337
Synonyms: (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-hydroxy-propanoate;Fmoc-L-Ser-OH;
EINECS: -0
Density: 1.362 g/cm3
Melting Point: 104-106 °C
Boiling Point: 599.3 °C at 760 mmHg
Flash Point: 316.2 °C
Appearance: White to off-white crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 22-24/25-26
PSA: 95.86000
LogP: 2.36150
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Specification

The Fmoc-L-Serine is an organic compound with the formula C18H17NO5. The IUPAC name of this chemical is (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-hydroxypropanoate. With the CAS registry number 73724-45-5, it is also named as L-Serine, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-. The product's categories are Protected Amino Acids; Amino Acids; Serine [Ser, S]; Fmoc-Amino Acids and Derivatives; Amino Acids (N-Protected); Biochemistry; Fmoc-Amino Acids; Fmoc-Amino Acid Series. Besides, it should be stored in a closed cool and dry place.

Physical properties about Fmoc-L-Serine are: (1)ACD/LogP: 2.66; (2)ACD/LogD (pH 5.5): 0.21; (3)ACD/LogD (pH 7.4): -1; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.35; (7)ACD/KOC (pH 7.4): 1; (8)#H bond acceptors: 6; (9)#H bond donors: 3; (10)#Freely Rotating Bonds: 7; (11)Polar Surface Area: 65.07 Å2; (12)Index of Refraction: 1.629; (13)Molar Refractivity: 85.44 cm3; (14)Molar Volume: 240.2 cm3; (15)Polarizability: 33.87×10-24cm3; (16)Surface Tension: 63.7 dyne/cm; (17)Density: 1.362 g/cm3; (18)Flash Point: 316.2 °C; (19)Enthalpy of Vaporization: 93.83 kJ/mol; (20)Boiling Point: 599.3 °C at 760 mmHg; (21)Vapour Pressure: 3.27E-15 mmHg at 25°C.

Preparation: this chemical can be prepared by O-(tert-butyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-L-serine. This reaction will need reagent Et3SiH, CF3CO2H and solvent CH2Cl2. The reaction time is 15 min at ambient temperature. The yield is about 99%.



Uses of Fmoc-L-Serine: it can be used to produce (S)-3-[(9-Fluorenyl)methoxycarbamoyl]oxeatn-2-one. It will need reagent PPh3, dimethyl azodicarboxylate. The yield is about 73%.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, do not breathe dust and avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O)[C@@H](NC(=O)OCC3c1ccccc1c2c3cccc2)CO
(2)InChI: InChI=1/C18H17NO5/c20-9-16(17(21)22)19-18(23)24-10-15-13-7-3-1-5-11(13)12-6-2-4-8-14(12)15/h1-8,15-16,20H,9-10H2,(H,19,23)(H,21,22)/t16-/m0/s1
(3)InChIKey: JZTKZVJMSCONAK-INIZCTEOBO
(4)Std. InChI: InChI=1S/C18H17NO5/c20-9-16(17(21)22)19-18(23)24-10-15-13-7-3-1-5-11(13)12-6-2-4-8-14(12)15/h1-8,15-16,20H,9-10H2,(H,19,23)(H,21,22)/t16-/m0/s1
(5)Std. InChIKey: JZTKZVJMSCONAK-INIZCTEOSA-N