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75-69-4

Basic Information
CAS No.: 75-69-4
Name: Fluorotrichloromethane
Article Data: 140
Molecular Structure:
Molecular Structure of 75-69-4 (Fluorotrichloromethane)
Formula: CCl3F
Molecular Weight: 137.368
Synonyms: Daiflon S 1;Dymel 11;Electro CF 11;F 11;F 11 (halocarbon);FC 11;FC 11 (halocarbon);FKW 11;Fluon 11;Fluorochloroform;Fluorotrichloromethane;Freon 11;Freon11A;Freon MF;Frigen 11;Frigen 11A;Frigen S 11;Fron 11;Genetron 11;Genetron 11SBA;Halon 11;Isceon 131;Isotron 11;Kaltron 11;Khladon 11;Ledon11;Monofluorotrichloromethane;Propellant 11;R 11;R 11 (refrigerant);R11SS;Refrigerant 11;Refrigerant R 11;Trichlorofluorocarbon;Trichlorofluoromethane;Trichloromethyl fluoride;Trichloromonofluoromethane;AlgofreneType 1;Arcton 11;Asahifron 11;CFC 11;Chladone 11;Daiflon 11;
EINECS: 200-892-3
Density: 1.621 g/cm3
Melting Point: -111°C
Boiling Point: 26.8 °C at 760 mmHg
Flash Point: 2°C
Solubility: Water Solubility : insoluble. 0.124 g/100 mL
Appearance: colourless liquid
Hazard Symbols: HarmfulXn; DangerousN
Risk Codes: 20-59
Safety: 23-24/25-59-61
Transport Information: UN 2517
PSA: 0.00000
LogP: 2.28360
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Chemistry

IUPAC Name: Trichloro(fluoro)methane
Synonyms: Algofrene Type 1 ; Algofrenetype1 ; Arcton 11 ; Arcton 9 ; Arcton11 ; Arcton9 ; Asahifron11 ; Caswellno.878
CAS: 75-69-4
MF: CCl3F
MW: 137.37
MS:
EINECS: 200-892-3
Product Categories: CFC ; Refrigerants ; Organics ; CFCsChemical Class ; FluoroVolatiles/ Semivolatiles ; Allergens ; Alpha Sort ; ChloroChemical Class ; Cosmetics ; Halogenated ; TP - TZ ; T-ZAlphabetic
Mol File: 75-69-4.mol
Surface Tension: 26.3 dyne/cm 
Density: 1.621 g/cm
Flash Point: 2 °C
Melting Point: -111°C
Boiling : 23.8°C 
Enthalpy of Vaporization: 26.15 kJ/mol 
Boiling Point: 26.8 °C at 760 mmHg 
Vapour Pressure: 714 mmHg at 25°C
Density : 1.494
Refractive index : 1.382
Storage temp:  2-8°C
Water Solubility:  insoluble. 0.124 g/100 mL
Merck : 13,9714
Stability: Stable. Incompatible with bronze, silver, copper, beryllium, alkali and alkaline earth metals. 

Uses

1. Trichlorofluoromethane (75-69-4)  is mainly used for  refrigerant of medium temperature, extraction agents, fire extinguishing agent.
2. Trichlorofluoromethane (75-69-4) is used as foam blowing agents of polyurethane, which is also used to produce sponge, medicine and pesticide, etc.
3. It is less toxic than chlorine hydrocarbons

Safety Profile

 

Hazard Codes:  Xn,Xi ,N,T,F
Risk Statements: 11-59-36/37/38-20/21/22-39/23/24/25
11:  Highly Flammable
59:  Trichlorofluoromethane (75-69-4) is dangerous for the ozone layer
36/37/38:  Irritating to eyes, respiratory system and skin
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed
39/23/24/25:  Toxic: danger of very serious irreversible effects through inhalation, in contact with
Safety Statements:  23-24/25-59-61-45-36/37-26-16-7
23:  Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25:  Avoid contact with skin and eyes
59:  Refer to manufacturer/supplier for information on recovery/recycling
61:  Avoid release to the environment. Refer to special instructions safety data sheet
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37:  Wear suitable protective clothing and gloves
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
16:  Keep away from sources of ignition - No smoking
7:  Keep container tightly closed 
RIDADR : 3082
RTEC:S  PB6125000
Hazard Note:  Irritant

Specification

1.Chemical Properties:Trichlorofluoromethane (75-69-4) colourless liquid
2.General Description: A clear light colored liquid. Nearly odorless. Denser than water. Poses low acute health hazard to humans. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.
3.Air & Water Reactions: Water soluble. Hydrolyzed slowly.
4.Reactivity Profile :Trichlorofluoromethane is incompatible with alkali or alkaline earth metals, powdered aluminum, zinc and beryllium. Trichlorofluoromethane reacts violently with barium and lithium.
5.Health Hazard :Breathing concentrations approaching 10% in air will cause dizziness and drowsiness. Contact with tissues may cause frostbite.
6.Fire Hazard :Special Hazards of Combustion Products: Produces irritating and toxic products when heated to decomposition temperatures.