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765-58-2

Basic Information
CAS No.: 765-58-2
Name: 2-Bromo-5-methylthiophene
Article Data: 34
Molecular Structure:
Molecular Structure of 765-58-2 (2-Bromo-5-methylthiophene)
Formula: C5H5BrS
Molecular Weight: 177.065
Synonyms: 5-Bromo-2-methylthiophene;5-Methyl-2-bromothiophene;
EINECS: 212-151-1
Density: 1.589 g/cm3
Melting Point: 58oC
Boiling Point: 176.7 °C at 760 mmHg
Flash Point: 60.6 °C
Appearance: colorless to light yellow liquid
Hazard Symbols: IrritantXi
Risk Codes: 20/21/22-36/37/38
Safety: 23-36/37/39
PSA: 28.24000
LogP: 2.81900
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Specification

The 2-Bromo-5-methylthiophene is an organic compound with the formula C5H5BrS. The IUPAC name of this chemical is 2-bromo-5-methylthiophene. With the CAS registry number 765-58-2, it is also named as Thiophene, 2-bromo-5-methyl-. The product's categories are Azoles; Blocks; Bromides; Sulphur Derivatives; Thiophene & Benzothiophene; Thiophens; Halogenated Heterocycles; Heterocyclic Building Blocks; Thiophenes; Thiophenes Building Blocks. Besides, it should be stored at temperature of 2 - 8 °C.

Physical properties about 2-Bromo-5-methylthiophene are: (1)ACD/LogP: 3.21; (2)ACD/LogD (pH 5.5): 3.21; (3)ACD/LogD (pH 7.4): 3.21; (4)ACD/BCF (pH 5.5): 161.49; (5)ACD/BCF (pH 7.4): 161.49; (6)ACD/KOC (pH 5.5): 1324.96; (7)ACD/KOC (pH 7.4): 1324.96; (8)Polar Surface Area: 28.24 Å2; (9)Index of Refraction: 1.581; (10)Molar Refractivity: 37.15 cm3; (11)Molar Volume: 111.3 cm3; (12)Polarizability: 14.72×10-24cm3; (13)Surface Tension: 39.1 dyne/cm; (14)Density: 1.589 g/cm3; (15)Flash Point: 60.6 °C; (16)Enthalpy of Vaporization: 39.6 kJ/mol; (17)Boiling Point: 176.7 °C at 760 mmHg; (18)Vapour Pressure: 1.45 mmHg at 25°C.

Preparation: this chemical can be prepared by 2-methyl-thiophene. This reaction will need reagent NBS. The yield is about 92%.


Uses of 2-Bromo-5-methylthiophene: it can be used to produce 5,5'-dimethyl-[2,2']bithiophenyl at temperature of 25 °C. It will need reagent t-AmONa, Ni(OAc)2, 2,2'-bipyridine and solvent tetrahydrofuran with reaction time of 1.5 s. The yield is about 73%.

When you are using this chemical, please be cautious about it as the following:
It is harmful by inhalation, in contact with skin and if swallowed. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection and do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).

You can still convert the following datas into molecular structure:
(1)SMILES: Brc1sc(cc1)C
(2)InChI: InChI=1/C5H5BrS/c1-4-2-3-5(6)7-4/h2-3H,1H3
(3)InChIKey: ACDLOOGOFKSUPO-UHFFFAOYAV
(4)Std. InChI: InChI=1S/C5H5BrS/c1-4-2-3-5(6)7-4/h2-3H,1H3
(5)Std. InChIKey: ACDLOOGOFKSUPO-UHFFFAOYSA-N