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766-09-6

Basic Information
CAS No.: 766-09-6
Name: 1-Ethylpiperidine
Article Data: 98
Molecular Structure:
Molecular Structure of 766-09-6 (1-Ethylpiperidine)
Formula: C7H15N
Molecular Weight: 113.203
Synonyms: N-Ethylpiperidine;NSC 2090;
EINECS: 212-161-6
Density: 0.837 g/cm3
Melting Point: -20 °C
Boiling Point: 125.6 °C at 760 mmHg
Flash Point: 18.9 °C
Solubility: water: 50 g/L
Appearance: clear colourless to slightly yellowish liquid
Hazard Symbols: FlammableF,HarmfulXn
Risk Codes: 11-20/22-36/37/38
Safety: 26-36/37/39
Transport Information: UN 2386 3/PG 2
PSA: 3.24000
LogP: 1.43010
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Chemistry

IUPAC Name: 1-Ethylpiperidine
CAS: 766-09-6
Formula : C7H15N
Molecular Weight: 113.2
Molecular Structure of 1-Ethylpiperidine (766-09-6):
 
Density: 0.837 g/cm3 
Flash Point: 18.9 °C
Melting Point: -20 °C 
Boiling Point: 125.6 °C at 760 mmHg  
Index of Refraction: 1.444 
Molar Refractivity: 35.95 cm
Molar Volume: 135 cm3 
Polarizability: 14.25×10-24cm
Surface Tension: 26.7 dyne/cm 
Enthalpy of Vaporization: 36.35 kJ/mol 
Vapour Pressure: 12.1 mmHg at 25°C
Appearance: clear colourless to slightly yellowish liquid
Water Solubility: 3.461e+004(mg/L) at 25°C
Product Categories: piperidine;building blocks;heterocyclic building blocks;piperidines.

Toxicity Data With Reference

1.    

eye-rbt 50 mg/5M

    BJIMAG    British Journal of Industrial Medicine. 23 (1966),153.
2.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00374 .
3.    

scu-rbt LDLo:100 mg/kg

    BDCGAS    Berichte der Deutschen Chemischen Gesellschaft. 34 (1901),2408.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous and subcutaneous routes. An eye irritant. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx.
Safety Information about 1-Ethylpiperidine (766-09-6):
Hazard Codes: 
F:   
Xn:
Risk Statements about 1-Ethylpiperidine (766-09-6):
R11: Highly Flammable.
R20/22: Harmful by inhalation and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements about 1-Ethylpiperidine (766-09-6):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 2386 3/PG 2
WGK Germany: 1
RTECS: TN0250000
F10: Keep under argon.
F23: Sensitive to air.
HazardClass: 3
PackingGroup: II

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Specification

  The chemical synonyms of 1-Ethylpiperidine (766-09-6) are 1-Ethvlpiperidine ; 1-Ethylpiperidene ; 1-Ethylpiperidin ; 1-Ethyl-piperidin ; Ethylpiperidylamnie ; Aethylpiperidin ; 1-Ethylpiperidine ; N-ethylpiperidine .It may cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.It may be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas. Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.