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Basic Information
CAS No.: 7696-12-0
Name: Tetramethrin
Molecular Structure:
Molecular Structure of 7696-12-0 (Tetramethrin)
Formula: C19H25NO4
Molecular Weight: 331.412
Synonyms: Cyclopropanecarboxylicacid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-,(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester (9CI);Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ester withN-(hydroxymethyl)-1-cyclohexene-1,2-dicarboximide (7CI,8CI);(1-Cyclohexene-1,2-dicarboximido)methyl chrysanthemumate;Bioneo-Pynamin;Insectol;Neo-Pynamin;Neo-Pynamin Forte;Phthalthrin;Pibutox;Pion 1;Pyrethrol L;d-Tetramethrin;Cyclopropanecarboxylicacid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-,(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester;
EINECS: 231-711-6
Density: 1.2 g/cm3
Melting Point: 60-80 ºC
Boiling Point: 453.2 ºC at 760 mmHg
Flash Point: 227.9 ºC
Solubility: 1.83 mg l-1 (25 °C)
Appearance: white crystals or powder
Hazard Symbols: HarmfulXn
Risk Codes: 20
Safety: 24/25
Transport Information: UN 2588
PSA: 63.68000
LogP: 2.90280
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    Product Name: Tetramethrin Synonyms: (+-)-cis/trans-phthalthrin;(1,3,4,5,6,7-hexahydro-1,3-dioxo-2h-isoindol-2-yl)methyl2,2-dimethyl-3-(2-me;(1-cyclo…Appearance:Solid powder Storage:Sealed,light and oxygen resistant Package:aluminum foil bag,carton

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Chemistry

IUPAC Name: (1,3-Dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl(1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
Empirical Formula: C19H25NO4
Molecular Weight: 331.4061 g/mol
Index of Refraction: 1.557 
Molar Refractivity: 88.96 cm3
Molar Volume: 276 cm3
Density: 1.2 g/cm3
Flash Point: 227.9 °C
Boiling Point: 453.2 °C at 760 mmHg
Vapour Pressure: 2.1E-08 mmHg at 25 °C 
EINECS: 231-711-6 
Melting Point: 60-80 °C
storage temp.: 0-6 °C 
Stability: Stable. Incompatible with strong oxidizing agents. 
Appearance: white crystals or powder
Product Categories: INSECTICIDE; PhthalimidesPesticides; PyrethroidsAlphabetic; Insecticides; Pesticides; TA - TE;Alpha sort; PyrethroidsPesticides & Metabolites; Q-ZAlphabetic
Structure of Tetramethrin (CAS NO.7696-12-0):
          
Classification Code: Agricultural Chemical; Insecticide; Insecticides; Mutation data; Pesticides; Skin / Eye Irritant

Uses

  Tetramethrin (CAS NO.7696-12-0) affects the insect's nervous system, and is commonly used as an insecticide.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
chicken LD50 oral 5gm/kg (5000mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 5, Pg. 220, 1976.
duck LD50 oral > 1gm/kg (1000mg/kg)   Pesticide Manual. Vol. 9, Pg. 807, 1991.
guinea pig LD50 skin > 20gm/kg (20000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

SKIN AND APPENDAGES (SKIN): HAIR: OTHER
Osaka Shiritsu Daigaku Igaku Zasshi. Journal of the Osaka City Medical Center. Vol. 16, Pg. 509, 1967.
mouse LC50 inhalation > 2gm/m3 (2000mg/m3)   Yakkyoku. Pharmacy. Vol. 36, Pg. 533, 1985.
mouse LD50 intraperitoneal 527mg/kg (527mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Oyo Yakuri. Pharmacometrics. Vol. 24, Pg. 179, 1982.
mouse LD50 oral 1gm/kg (1000mg/kg)   Agricultural and Biological Chemistry. Vol. 28, Pg. 914, 1965.
mouse LD50 skin > 15gm/kg (15000mg/kg)   Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 6, 1978.
mouse LD50 subcutaneous 1950mg/kg (1950mg/kg) BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: ATAXIA
Oyo Yakuri. Pharmacometrics. Vol. 24, Pg. 179, 1982.
quail LD50 oral > 1gm/kg (1000mg/kg)   Pesticide Manual. Vol. 9, Pg. 807, 1991.
rat LC50 inhalation > 2500mg/m3/3H (2500mg/m3)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A388, Pg. 1983,
rat LD50 intraperitoneal 548mg/kg (548mg/kg) BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: ATAXIA
Oyo Yakuri. Pharmacometrics. Vol. 24, Pg. 179, 1982.
rat LD50 intravenous 3500ug/kg (3.5mg/kg)   Agricultural and Biological Chemistry. Vol. 32, Pg. 628, 1968.
rat LD50 oral 4640mg/kg (4640mg/kg)   Yakkyoku. Pharmacy. Vol. 35, Pg. 1315, 1984.
rat LD50 skin > 2500mg/kg (2500mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT

KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 49(4), Pg. 90, 1984.
rat LD50 subcutaneous 5700mg/kg (5700mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED
Osaka Shiritsu Daigaku Igaku Zasshi. Journal of the Osaka City Medical Center. Vol. 16, Pg. 509, 1967.

Safety Profile

Hazard Codes of Neopinamine (CAS NO.7696-12-0): HarmfulXn
Risk Statements: 20
R20:Harmful by inhalation.
Safety Statements: 24/25
S24/25:Avoid contact with skin and eyes.

Specification

 Tetramethrin , its cas register number is 7696-12-0 now. It also can be called Bioneopynamin ; 3,4,5,6-Tetrahydrophthalimidomethyl (+-)-cis-trans-chrysanthemate ; and Cyclohexene-1-dicarboximidomethylchrysanthemate ; 1-Cyclohexene-1,2-dicarboximidomethyl-2,2-dimethyl-3-(2-methylpropenyl)cyclopropane carboxylate ; 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)methyl ester ; 2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid ester withN-(hydroxymethyl)-1-cyclohexene-1,2-dicarboximide ; 2,3,4,5-Tetrahydrophthalimidomethylchrysanthemate ; 3,4,5,6-Tetrahydro-phthalimidomethylester der dl-cis-trans-chrysanthemumsaeure .