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Basic Information
CAS No.: 7700-17-6
Name: CROTOXYPHOS
Molecular Structure:
Molecular Structure of 7700-17-6 (CROTOXYPHOS)
Formula: C14H19 O6 P
Molecular Weight: 314.275
Synonyms: 2-Butenoicacid, 3-[(dimethoxyphosphinyl)oxy]-, 1-phenylethyl ester, (E)-; Crotonic acid,3-hydroxy-, a-methylbenzylester, dimethyl phosphate, (E)- (8CI); 3-Hydroxycrotonic acid a-methylbenzyl ester dimethylphosphate; Ciodrin; Crotoxyfos; Crotoxyphos; Cyodrin; Dimethyl 2-(a-methylbenzyloxycarbonyl)-1-methylvinylphosphate; O,O-Dimethyl O-[1-methyl-2-(1-phenylcarbethoxy)vinyl] phosphate;Pantozol 1; SD 4294; Volfazol; trans-Crotoxyphos
EINECS: 231-720-5
Density: 1.198 g/cm3
Boiling Point: 365.6 °C at 760 mmHg
Flash Point: 188.5 °C
Solubility: 1g/L(room temperature)
Hazard Symbols: ToxicTDangerousN
Risk Codes: 24/25-50/53
Safety: 28-36/37-45-60-61
PSA: 80.87000
LogP: 3.61210
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Chemistry

Product Name: Crotoxyfos (CAS NO.7700-17-6)


Molecular Formula: C14H19O6P
Molecular Weight: 314.27g/mol
Mol File: 7700-17-6.mol
Einecs: 231-720-5
Boiling point: 365.6 °C at 760 mmHg
Flash Point: 188.5 °C
Density: 1.198 g/cm3
Surface Tension: 40.2 dyne/cm
Enthalpy of Vaporization: 61.19 kJ/mol
Vapour Pressure: 1.55E-05 mmHg at 25°C
XLogP3: 3.3
H-Bond Donor: 0
H-Bond Acceptor: 6
Product Categories: AcaricidesPesticides and Metabolites; Alpha sort; C; CAlphabetic; CO - CZPesticides; Insecticides; Organophorous; Pesticides; Pesticides and Metabolites

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 56200ug/kg (56.2mg/kg)   Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983.
cat LD50 oral 802mg/kg (802mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(6), Pg. 30, 1973.
chicken LD50 oral 111mg/kg (111mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Toxicology and Applied Pharmacology. Vol. 7, Pg. 606, 1965.
mammal (species unspecified) LC50 inhalation 88mg/m3 (88mg/m3)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(5), Pg. 72, 1990.
mammal (species unspecified) LD50 unreported 125mg/kg (125mg/kg)   "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971Vol. -, Pg. 313, 1971.
mouse LD50 intraperitoneal 71mg/kg (71mg/kg)   Journal of Pharmacy and Pharmacology. Vol. 19, Pg. 612, 1967.
mouse LD50 intravenous 4500ug/kg (4.5mg/kg)   Journal of Pharmacy and Pharmacology. Vol. 19, Pg. 612, 1967.
mouse LD50 oral 39800ug/kg (39.8mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(6), Pg. 30, 1973.
mouse LD50 subcutaneous 15mg/kg (15mg/kg)   Journal of Pharmacy and Pharmacology. Vol. 19, Pg. 612, 1967.
mouse LD50 unreported 40mg/kg (40mg/kg)   Tsitologiya i Genetika. Cytology and Genetics. For English translation, see CYGEDX. Vol. 16(1), Pg. 45, 1982.
rabbit LD50 skin 385mg/kg (385mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 244, 1966.
rat LD50 oral 38400ug/kg (38.4mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(6), Pg. 30, 1973.
rat LD50 skin 202mg/kg (202mg/kg)   World Review of Pest Control. Vol. 9, Pg. 119, 1970.
rat LD50 subcutaneous 47mg/kg (47mg/kg)   British Journal of Pharmacology. Vol. 40, Pg. 124, 1970.
rat LD50 unreported 64800ug/kg (64.8mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(3), Pg. 57, 1985.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of Crotoxyfos (CAS NO.7700-17-6):
Hazard Codes: T,N
Risk Statements: 24/25-50/53
24:  Toxic in contact with skin 
25:  Toxic if swallowed 
50:  Very Toxic to aquatic organisms  
53:  May cause long-term adverse effects in the aquatic environment
Safety Statements: 28-36/37-45-60-61
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
60:  This material and/or its container must be disposed of as hazardous waste 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 

Specification

 Crotoxyfos ,its CAS NO. is 7700-17-6,the synonyms is Ciodrin(r);crotoxyphos ; Dimethyl (e)-1-methyl-2-(1-phenylethoxycarbonyl) vinyl phosphate ; A-methylbenzyl-3-hydroxycrotonate-dimethylphosphate ; 1-Methylbenzyl-3-[dimethoxyphos-phinyloxy]cis-crotonate ; 1-Methylbenzyl-3-(dimethoxyphosphinyloxo)isocrotonate ; 1-Phenylethyl (2e)-3-[(dimethoxyphosphoryl)oxy]-2-butenoate ; 1-Phenylethyl 3-(dimethoxyphosphinoyloxy)isocrotonate .