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| CAS No.: | 7787-62-4 |
|---|---|
| Name: | Bismuth pentafluoride |
| Article Data: | 21 |
| Molecular Structure: | |
|
|
|
| Formula: | BiF5 |
| Molecular Weight: | 303.972 |
| Synonyms: | bithmuth tribromide;bismuth (III) bromide;bismuth(III) chloride;Wismut(III)-bromid;tribromobismuthine;Bismuth pentafluoride;Bismuth tribromide;Bismuth bromide;bismuth fluoride;Bismuthine,tribromo;tribromobismuth; |
| EINECS: | 232-125-3 |
| Density: | g/cm3 |
| Melting Point: | 550°C (subl.) |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Solubility: | violent reaction with H2O to form BiF3 and ozone [MER06] |
| Hazard Symbols: | O,C |
| Risk Codes: | 8-34 |
| Safety: | An irritant poison via ingestion and inhalation routes. Decomposes vigorously and sometimes ignites on contact with moisture to yield O3 and bismuth trifluoride. Very dangerous. Reacts violently with water and petrolatum above 50°, and acids at room temperature, liberating much heat and ozone. When heated to decomposition it emits highly toxic fumes of F−. See also FLUORIDES and OZONE. |
| PSA: | 0.00000 |
| LogP: | -14.98000 |
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Chemistry
IUPAC Name: pentafluorobismuth
EINECS: 232-125-3
CAS NO: 7787-62-4
Molecular Formula Bismuth pentafluoride (CAS NO.7787-62-4): BiF5
Molecular Weight: 303.9735
Molecular Structure:
.bmp)
Production
BiF5 can be prepared by reacting BiF3 with F2 at 500 °C.
BiF3 + F2 → BiF5
Safety Profile
Hazard Codes: 
O,
C
Risk Statements: 8-34
R8: Contact with combustible material may cause fire.
R34: Causes burns.
Safety Statements: 17-26-27-36/37/39
S17: Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27: Take off immediately all contaminated clothing.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3084 8/PG 1
WGK Germany: 3
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: II
An irritant poison via ingestion and inhalation routes. Decomposes vigorously and sometimes ignites on contact with moisture to yield O3 and bismuth trifluoride. Very dangerous. Reacts violently with water and petrolatum above 50°, and acids at room temperature, liberating much heat and ozone. When heated to decomposition it emits highly toxic fumes of F−. See also FLUORIDES and OZONE.