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Basic Information
CAS No.: 80-47-7
Name: 8-P-MENTHYL HYDROPEROXIDE
Molecular Structure:
Molecular Structure of 80-47-7 (8-P-MENTHYL HYDROPEROXIDE)
Formula: C10H20 O2
Molecular Weight: 172.268
Synonyms: p-Menth-8-ylhydroperoxide (7CI,8CI); 1-Methyl-1-(4-methylcyclohexyl)ethyl hydroperoxide;Permentha H; Trigonox NT; p-Menthane hydroperoxide
EINECS: 201-281-4
Density: 0.91-0.94g/cm3(15.5℃/15.5℃)
Boiling Point: 255.8°C at 760 mmHg
Flash Point: 53 C
Solubility:

Stability

    Stable. Combustible. Incompatible with strong oxidizing agents,reducing agents. Powerful oxidizer - reacts readily with manyorganic chemicals.

Toxicology

    Skin and eye irritant.

    colourless to slightly yellow viscous liquid

Hazard Symbols: Strong oxidizing agent, dangerous in contact with organic materials. Strong irritant to skin and eyes.
Risk Codes: 7-20-34
Safety: Questionable carcinogen with experimental tumorigenic data. Mutation data reported. An irritant and powerful oxidizer. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, ORGANIC.
PSA: 29.46000
LogP: 3.08090
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Chemistry

MF: C10H20O2
MW: 172.26
EINECS: 201-281-4
Density: 0.956 g/cm3 
Flash Point: 108.5 °C 
Index of Refraction: 1.458
Enthalpy of Vaporization: 57.3 kJ/mol 
Boiling Point: 255.8 °C at 760 mmHg
 Vapour Pressure: 0.00242 mmHg at 25°C
Air & Water Reactions: Insoluble in water.
Chemical Properties: colourless to slightly yellow viscous liquid
IUPAC Name: 1-(2-Hydroperoxypropan-2-yl)-4-methylcyclohexane
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, reducing agents. Powerful oxidizer - reacts readily with many organic chemicals.
Synonyms: Hydroperoxide,1-methyl-1-(4-methylcyclohexyl)ethyl ; P-menth-8-ylhydroperoxide ; P-Menthane-8-hydroperoxide ; 8-P-methyl hydroperoxide ; p-Menthyl hydroperoxide(technically pure) ; 1-Methyl-1-(4-methylcyclohexyl)ethyl hydroperoxide ; 8-P-Menthane hydroperoxide
Following is the molecular structure of P-Menthane-8-hydroperoxide (80-47-7):

Production

Reactivity Profile of P-Menthane-8-hydroperoxide (80-47-7):  Most alkyl monohydroperoxides are liquid, the explosivity of the lower members (e.g., methyl hydroperoxide, or possibly due to traces of the dialkyl peroxides) decreasing with increasing chain length and branching [Bretherick 2nd ed. 1979. p. 10].

Toxicity Data With Reference

1.    

mmo-sat 33 µg/plate

    EMMUEG    Environmental and Molecular Mutagenesis. 11 (Suppl 12)(1988),1.

Safety Profile

Questionable carcinogen with experimental tumorigenic data. Mutation data reported. An irritant and powerful oxidizer. When heated to decomposition it emits acrid smoke and irritating fumes.
Safety Information of P-Menthane-8-hydroperoxide (80-47-7):
Hazard Codes: O,C
O: Oxidizing  C: Corrosive
Risk Statements: 7-20-34
7: May cause fire 
20: Harmful by inhalation 
34: Causes burns  
Safety Statements: 3/7-14-36/37/39-45
3/7: Keep container tightly closed in a cool place 
14: Keep away from ... (incompatible materials to be indicated by the manufacturer) 
36/37/39: Wear suitable protective clothing, gloves and eye/face protection 
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
RIDADR: 3105
HazardClass: 5.2
PackingGroup: II