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Basic Information
CAS No.: 8002-09-3
Name: Pine oil
Molecular Structure:
Molecular Structure of 8002-09-3 (Pine oil)
Formula: N/A
Molecular Weight: 0
Synonyms: Oils, pine;Oils, essential, pine;C 30 (pine oil);Dertol 90;Essential pine oil;Glico 150;Glidsol 150;Oil of pine;Oils, pine wood;Oils, pine, synthetic;Oulo 102;Peramin HPA;Pine Oil C 30;Pine oil,synthetic;Pine wood oil;Polyiff 272;RT 1712;Unipine 80;Unipine 85;Yarmor;Yarmor 302;Yarmor 60;Yarmor F;Essential oils, pine;
EINECS: 232-293-8
Density: 0.86 g/mL at 25 °C(lit.)
Melting Point: -55 °C(lit.)
Boiling Point: 153-175 °C(lit.)
Flash Point: 86 °F
Appearance: clear colorless to light amber colored liquid
Hazard Symbols: HarmfulXn, DangerousN
Risk Codes: 36/38-43-65
Safety: 36/37-46-61-62
Transport Information: UN 1299 3/PG 3
PSA: 0.00000
LogP: 0.00000
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    Items Standard Result Assay 98%min ---------------------------------------------------------------------------------------------

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Chemistry

Product Name: Pine oil
Synonyms of Pine oil (CAS NO.8002-09-3): Arizole ; C 30 (pine oil) ; Caswell No. 665 ; Dertol 90 ; Dwarf pine needle oil ; EPA Pesticide Chemical Code 067002 ; Essential oils, pine ; Essential pine oil ; Glico 150 ; Glidsol 150 ; Oil of fir - - Siberian ; Oil of pine ; Oils, essential, pine ; Oils, pine ; Oils, pine wood ; Oils, pine, synthetic ; Oleum abietis ; Oulo 02 ; Pine Oil C 30 ; Pine needle oil ; Pine oil absolute ; Pine oil, synthetic ; Pine oil, white (Pinus spp.) ; Pine wood oil ; Polyiff 272 ; RT 1712 ; Terpentinoel ; Terpentinoel [German] ; Unipine ; Unipine 80 ; Unipine 85 ; Yarmor ; Yarmor 302 ; Yarmor 60 ; Yarmor F ; Yarmor pine oil ; Yarmor pine oil (Pinus palustris MilL.)
CAS NO: 8002-09-3
Classification Code: Agricultural Chemical ; Human Data ; Insect attractant, repellent and chemosterilant ; Insecticide ; Skin / Eye Irritant ; TSCA UVCB
Melting point: −55 °C 
Boiling Point: 153-175 °C
Density: 0.86 g/mL at 25 °C
Vapor Density: 4.84
Vapor Pressure: 4 mm Hg
Refractive Index: n20/D 1.515
Flash Point: 86 °F

Uses

  Pine oil (CAS NO.8002-09-3) is used in aromatherapy, as a scent in bath oils, as a cleaning product, and as a lubricant in small and expensive clockwork instruments. It is naturally deodorizing, and antibacterial. It may also be used varyingly as a disinfectant, massage oil and an antiseptic. Industrially, pine oil is used in metal extraction from ores. It is a phenolic disinfectant that is mildly antiseptic. Pine oil disinfectants are relatively inexpensive and widely available.

Production

  Pine oil (CAS NO.8002-09-3) can be extracted from pine but is also synthetically made from turpentine, especially the α-pinene fraction, by reaction with aqueous acid.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
man TDLo oral 4700mg/kg (4700mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: ATAXIA

BEHAVIORAL: HEADACHE
Archives of Toxicology. Vol. 49, Pg. 73, 1981.
rabbit LD50 skin 5gm/kg (5000mg/kg)   Food and Chemical Toxicology. Vol. 21, Pg. 875.1983,
rat LD50 oral 3200mg/kg (3200mg/kg)   Food and Chemical Toxicology. Vol. 21, Pg. 875, 1983.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes of Pine oil (CAS NO.8002-09-3): Xn,N
Risk Statements: 36/38-43-65
36/38:  Irritating to eyes and skin 
43:  May cause sensitization by skin contact 
65:  Harmful: May cause lung damage if swallowed
Safety Statements: 36/37-46-61-62
36/37:  Wear suitable protective clothing and gloves 
46:  If swallowed, seek medical advice immediately and show this container or label 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 
62:  If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
RIDADR: UN 1299 3/PG 3
WGK Germany:  2
RTECS: YO8400000
HazardClass: 3.2
PackingGroup:  III
Moderately toxic by ingestion. Mildly toxic by skin contact. A weak allergen and a severe irritant to skin and mucous membranes. Human systemic effects by ingestion: excitement, ataxia, headache. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. Moderate spontaneous heating. To fight fire, use foam, CO2, dry chemical. Used as an odorant, disinfectant, solvent, wetting agent, and frothing agent.

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid