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| CAS No.: | 8049-17-0 |
|---|---|
| Name: | Ferric silicon |
| Molecular Structure: | |
 |
|
| Formula: | FeSi2 |
| Molecular Weight: | 83.90 |
| Synonyms: | Ferrosilicon |
| Density: | 4,75 g/cm3 |
| Melting Point: | 1360ºC |
| Solubility: | Solubility in water: insoluble |
| Appearance: | Silver-gray coarse powder |
| Safety: | Moderate inhalation hazard. Low skin toxicity. Reaction with moisture releases hydrogen and acetylene gases, which then ignite; impurities in the alloy may liberate such poisonous and reactive gases as phosphine and arsine. Dry mixtures with sodium hydroxide react incandescently when water is added. Reaction with acid, acid fumes, or oxidizing materials can emit toxic fumes. Reaction hazards increase with decreasing particle size. |
| Transport Information: | UN1408 |
| PSA: | 0.00000 |
| LogP: | 0.00000 |
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Chemistry
Chemical Name: Ferric silicon
IUPAC NAME: (1-Cyclohexylaziridin-2-yl)-phenylmethanone
CAS No.: 8049-17-0
Molecular Formula: FeSi2
Molecular Weight: 112.02 g/mol
Density: 4,75 g/cm3
Following is the structure of Ferrosilicon (8049-17-0):
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The chemical synonymous of Ferrosilicon (8049-17-0) are Iron silicide ; Ferric silicon ; Ferrosilicon,with not less than 30% but less than 90% silicon ; Ferrosilicon ; Ferro silica ; Nlt72%Si ; Alcoa ferrosilicon ; Abel ferro silicon 75/80
Uses
Ferrosilicon (8049-17-0) is mainly used to add silicon to iron and steel.
Toxicity Data With Reference
| 1. | skn-rbt LD50:>20 g/kg | NTIS** National Technical Information Service . (Springfield, VA 22161)(Formerly U.S. Clearinghouse for Scientific and Technical Information) AD-A062-138 . | ||
| 2. | ihl-rat TCLo:194 mg/m3/6H/26W-I | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 22 (6)(1978),28. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderate inhalation hazard. Low skin toxicity. Reaction with moisture releases hydrogen and acetylene gases, which then ignite; impurities in the alloy may liberate such poisonous and reactive gases as phosphine and arsine. Dry mixtures with sodium hydroxide react incandescently when water is added. Reaction with acid, acid fumes, or oxidizing materials can emit toxic fumes. Reaction hazards increase with decreasing particle size.
Attention:
1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
3. Health Hazard: Exposure can cause irritation of eyes, nose and throat. Toxic if inhaled or ingested.
Standards and Recommendations
DOT Classification: 4.3; Label: Dangerous When Wet
Specification
Ferrosilicon (8049-17-0) is a ferroalloy an alloy of iron and silicon with between 15 and 90% silicon. It contains a high proportion of iron silicides. Its melting point is about 1200 °C to 1250 °C with a boiling point of 2355 °C. It also contains about 1 to 2% of calcium and aluminium.It is used in steelmaking and foundries as a source of silicon in production of carbon steels, stainless steels, and other ferrous alloys for its deoxidizing properties, to prevent loss of carbon from the molten steel (so called blocking the heat) ; ferromanganese, spiegeleisen, silicides of calcium, and many other materials are used for the same purpose. It can be used to make other ferroalloys. Ferrosilicon is also used for manufacture of silicon, corrosion-resistant and high-temperature resistant ferrous silicon alloys, and silicon steel for electromotors and transformer cores. In manufacture of cast iron, ferrosilicon is used for inoculation of the iron to accelerate graphitization. In arc welding, ferrosilicon can be found in some electrode coatings.Ferrosilicon is a basis for manufacture of prealloys like magnesium ferrosilicon (FeSiMg), used for modification of melted malleable iron;FeSiMg contains between 3-42% of magnesium and small amounts of rare earth metals. Ferrosilicon is also important as an additive to cast irons for controlling the initial content of silicon.It is produced by reduction of silica or sand with coke in presence of scrap iron, millscale, or other source of iron. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct.Ferrosilicon is used by the military to quickly produce hydrogen for balloons by the ferrosilicon method. The chemical reaction uses sodium hydroxide, ferrosilicon, and water. The generator is small enough to fit a truck and requires only a small amount of electric power, the materials are stable and not combustible, and they do not generate hydrogen until mixed.