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83-27-2

Basic Information
CAS No.: 83-27-2
Name: Diethyl sec-butylmalonate
Article Data: 19
Molecular Structure:
Molecular Structure of 83-27-2 (Diethyl sec-butylmalonate)
Formula: C11H20O4
Molecular Weight: 216.277
Synonyms: Malonicacid, sec-butyl-, diethyl ester (6CI,7CI,8CI);Propanedioic acid,(1-methylpropyl)-, diethyl ester (9CI);(1-Methylpropyl)propanedioic aciddiethyl ester;Diethyl sec-butylmalonate;NSC 127865;NSC 30679;NSC 41157;sec-Butylmalonic acid, diethyl ester;Diethyl (1-Methylpropyl)malonate;Malonic acid, sec-butyl-, diethyl ester;Propanedioic acid, (1-methylpropyl)-, diethyl ester;
EINECS: 201-463-3
Density: 0.992 g/cm3
Boiling Point: 247.5 °C at 760 mmHg
Flash Point: 103.1 °C
Safety: 24/25
PSA: 52.60000
LogP: 1.77490
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  • Diethyl sec-butylmalonate  CAS NO.83-27-2

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    Diethyl sec-butylmalonate CAS NO.83-27-2

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  • Diethyl 2-(sec-butyl)malonate83-27-2

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  • DIETHYL SEC-BUTYLMALONATE

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Specification

The Diethyl sec-butylmalonate, with the CAS registry number 83-27-2 and EINECS registry number 201-463-3, has the systematic name of diethyl butan-2-ylpropanedioate. And the molecular formula of the chemical is C11H20O4. What's more, while dealing with this chemical, you should avoid contacting with skin and eyes.

The characteristics of Diethyl sec-butylmalonate are as followings: (1)ACD/LogP: 2.46; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.46; (4)ACD/LogD (pH 7.4): 2.46; (5)ACD/BCF (pH 5.5): 43.66; (6)ACD/BCF (pH 7.4): 43.66; (7)ACD/KOC (pH 5.5): 519.51; (8)ACD/KOC (pH 7.4): 519.5; (9)#H bond acceptors: 4; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 52.6 Å2; (13)Index of Refraction: 1.431; (14)Molar Refractivity: 56.47 cm3; (15)Molar Volume: 217.8 cm3; (16)Polarizability: 22.38×10-24cm3; (17)Surface Tension: 31 dyne/cm; (18)Density: 0.992 g/cm3; (19)Flash Point: 103.1 °C; (20)Enthalpy of Vaporization: 48.47 kJ/mol; (21)Boiling Point: 247.5 °C at 760 mmHg; (22)Vapour Pressure: 0.0256 mmHg at 25°C. 

Uses of Diethyl sec-butylmalonate: It can react with formaldehyde to produce Diethyl s-butylhydroxymethylmalonate. This reaction will need reagent K2CO3, and the menstruum dimethylsulfoxide. The reaction time is 30 hours with ambient temperature, and the yield is about 70%.   

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O=C(OCC)C(C(=O)OCC)C(CC)C
(2)InChI: InChI=1/C11H20O4/c1-5-8(4)9(10(12)14-6-2)11(13)15-7-3/h8-9H,5-7H2,1-4H3
(3)InChIKey: MIIZSUOEOUHAIZ-UHFFFAOYAK