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| CAS No.: | 86-57-7 | |||
|---|---|---|---|---|
| Name: | 1-Nitronaphthalene | |||
| Molecular Structure: | ||||
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| Formula: | C10H7 N O2 | |||
| Molecular Weight: | 173.171 | |||
| Synonyms: | 1-Nitro-naphthaline;1-Nitronaphthalene; NSC 9584; Nitrol; Nitrol (pesticide); a-Nitronaphthalene | |||
| EINECS: | 201-684-5 | |||
| Density: | 1.22 | |||
| Melting Point: | 58 - 60 C | |||
| Boiling Point: | 304 C | |||
| Flash Point: | 164 ºC | |||
| Solubility: | Insoluble | yellow to green crystalline powder | ||
| Hazard Symbols: |
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| Risk Codes: | R25;R40 | |||
| Safety: | Poison by intraperitoneal route. Mutation data reported. A skin, eye, and mucous membrane irritant. Flammable solid and combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical, or water spray. Explosive reaction with nitric acid + sulfuric acid above 60°C. Forms a sensitive explosive mixture with tetranitromethane. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITRONAPHTHALENE and NITRO COMPOUNDS of AROMATIC HYDROCARBONS. | |||
| Transport Information: | UN 2538 | |||
| PSA: | 45.82000 | |||
| LogP: | 3.27120 | |||
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Chemistry
IUPAC Name: 1-Nitronaphthalene
CAS: 86-57-7
Formula: C10H7NO2
Molecular Weight: 173.17
Molecular Structure of 1-Nitronaphthalene (86-57-7):
Density: 1.279 g/cm3
Flash Point: 150.3 °C
Boiling Point: 304 °C at 760 mmHg
Melting Point: 56 °C
Index of Refraction: 1.671
Molar Refractivity: 50.64 cm3
Molar Volume: 135.3 cm3
Polarizability: 20.07 10-24cm3
Surface Tension: 53.7 dyne/cm
Appearance: yellow crystalline solid
Enthalpy of Vaporization: 52.26 kJ/mol
Vapour Pressure: 0.00162 mmHg at 25°C
Water Solubility: 1.252e+004(mg/L) at 25°C
Product Categories: intermediates of dyes and pigments;nitro compounds;nitrogen compounds;organic building blocks;bBA - NIApplication CRMs;Nitro-PAH;alphabetic.
Toxicity Data With Reference
| 1. | mmo-sat 1 µg/plate | MUREAV Mutation Research. 122 (1983),243. | ||
| 2. | mma-sat 3300 ng/plate | ENMUDM Environmental Mutagenesis. 7 (Suppl 5)(1985),1. | ||
| 3. | ipr-rat LD50:86 mg/kg | JJATDK JAT, Journal of Applied Toxicology. 4 (1984),253. |
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 291.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 291.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 291.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-64 ,1978. . Reported in EPA TSCA Inventory.
Safety Profile
Poison by intraperitoneal route. Mutation data reported. A skin, eye, and mucous membrane irritant. Flammable solid and combustible liquid when exposed to heat or flame. To fight fire, use CO2, dry chemical, or water spray. Explosive reaction with nitric acid + sulfuric acid above 60°C. Forms a sensitive explosive mixture with tetranitromethane. When heated to decomposition it emits toxic fumes of NOx. See also 2-NITRONAPHTHALENE and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Safety Information about 1-nitronaphthalene (86-57-7):
Hazard Codes:
F: 
T: 
N: 
Risk Statements about 1-nitronaphthalene (86-57-7):
R11: Highly Flammable.
R25: Toxic if swallowed.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
R40: Limited evidence of a carcinogenic effect.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 1-nitronaphthalene (86-57-7):
S16: Keep away from sources of ignition - No smoking.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
S36/37/39: Irritating to eyes, respiratory system and skin.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
S60: This material and/or its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions safety data sheet.
RIDADR: UN 2538 4.1/PG 3
WGK Germany: 2
Hazard Note: Flammable/Toxic
HazardClass: 4.1
PackingGroup: III
HS Code: 29042000
Standards and Recommendations
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
Specification
The chemical synonyms of 1-Nitronaphthalene (86-57-7) are 1-Nitronaphthalene ; Alpha-nitronaphthalene ; 1-Nitronaftalen ; 1-Nitro-naphthalen ; Naphthalene,1-Nitro- ; Naphthalene,alpha-nitro .This product of 1-Nitronaphthalene (86-57-7) can be used as intermediates for fuel, pesticides, rubber chemicals and other organic synthesis.Handling and Storage of the product: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.Keep away from water and storage at 2-8°C.Personal Protective Equipment: Wear safety glasses and chemical goggles if splashing is possible. Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective clothing to minimize contact with skin.