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CAS No.: | 89-02-1 |
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Name: | 2,4-DINITROBENZENESULFONIC ACID |
Article Data: | 9 |
Molecular Structure: | |
Formula: | C6H4 N2 O7 S |
Molecular Weight: | 248.173 |
Synonyms: | 2,4-Dinitrobenzenesulfonicacid; NSC 152110; NSC 163960 |
Density: | 1.745 (estimate) |
Melting Point: |
95-98 °C(lit.) |
Solubility: | Soluble in methanol (2.5% w/v), slightly soluble in water. |
Appearance: | YELLOW TO YELLOW-BROWN CRYSTALLINE POWDER |
Hazard Symbols: | |
Risk Codes: | 34 |
Safety: | Poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of NOx and SOx. |
PSA: | 154.39000 |
LogP: | 2.87690 |
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Empirical Formula: C6H4N2O7S
Molecular Weight: 248.1702
EINECS: 201-876-9
Melting point: 95-98 °C(lit.)
Index of Refraction: 1.643
Density: 1.826 g/cm3
Structure of 2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1):
IUPAC Name: 2,4-Dinitrobenzenesulfonic acid
Product Categories: Intermediates of Dyes and Pigments;Organic Building Blocks;Sulfonic/Sulfinic Acids
2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1) has been used for dye intermediate.
2,4-Dinitrobenzenesulfonic acid (CAS NO.89-02-1) can be derived by sulfonation from 2,4 - Dinitrochlorobenzene . Take 1100L water into the sulfonation pot, and has it heated to 50 °C, then keep stirring fast when join 119kg light Magnesium oxide . Stirring a moment then add 750kg melt: 2,4 - Dinitrochlorobenzene , and heated to 65 °C, add 462kg weight Sodium sulfite solution (dubbed 4.5-5N concentration) in 4h. At last, when the reaction is completed, has them beng cooled to 55 °C. Adding Hydrochloric acid , then add 35kg salt, cooled to 20 °C, put it aside, filtering, then we will get the product.
1. | skn-rbt 500 mg/24H MOD | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,180. | ||
2. | eye-rbt 500 mg/24H MLD | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,180. | ||
3. | ivn-mus LD50:320 mg/kg | CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01550 . |
Reported in EPA TSCA Inventory.
Poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of NOx and SOx.
Hazard Codes: C
Risk Statements: 34
R34:Causes burns.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
2,4-Dinitrobenzenesulfonic acid ,its cas register number is 89-02-1. It also can be called 2,4-Dinitrophenylsulfonic acid ;and Kyselina 2,4-dinitrobenzensulfonova .