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92-67-1

Basic Information
CAS No.: 92-67-1
Name: [1,1'-Biphenyl]-4-amine
Article Data: 348
Cas Database
Molecular Structure:
Molecular Structure of 92-67-1 ([1,1'-Biphenyl]-4-amine)
Formula: C12H11N
Molecular Weight: 169.226
Synonyms: 4-Biphenylamine(8CI);(1,1'-Biphenyl-4-yl)amine;4-Amino-1,1'-biphenyl;4-Biphenylylamine;4-Phenylaniline;4-Phenylbenzenamine;NSC7660;Xenylamine;p-Aminobiphenyl;p-Biphenylamine;p-Phenylaniline;p-Xenylamine;
EINECS: 202-177-1
Density: 1.077 g/cm3
Melting Point: 52-54 °C(lit.)
Boiling Point: 302 °C at 760 mmHg
Flash Point: 152.2 °C
Solubility: 842 mg/L at 20–30 °C (quoted, Mercer et al., 1990)
Appearance: brownish yellow solid
Hazard Symbols: ToxicT,HarmfulXn
Risk Codes: 45-22-36/37/38-20/21/22
Safety: 53-45-36-26
Transport Information: UN 3077 9/PG 3
PSA: 26.02000
LogP: 3.51700
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Chemistry

IUPAC Standard InChIKey: DMVOXQPQNTYEKQ-UHFFFAOYSA-N
Synonyms: 4-adp;4-Aminodiphenyl;4-Aminobifenyl;4-aminobiphenyle;4-Aminodifenil;4-Bifenylamin;Aniline, p-phenyl-;biphenyl-4-ylamine;
The Molecular formula of 4-AMINODIPHENYL(92-67-1): C12H11N
The Molecular Weight of 4-AMINODIPHENYL(92-67-1): 169.22
Molecular Structure : 
EINECS: 202-177-1
Melting point: 52-54 °C(lit.)
Boiling point: 191 °C at 15 mm Hg(lit.)
Flash point: >110°C
Appearance: Brownish Yellow Solid
Merck: 13,1235

Uses

4-AMINODIPHENYL(92-67-1)is used as dye and pesticide intermediates.

Toxicity Data With Reference

1.   

mma-sat 2 µg/plate

   ENMUDM    Environmental Mutagenesis. 5 (Suppl 1)(1983),3.
2.   

dnd-esc 30 µmol/L

   MUREAV    Mutation Research. 89 (1981),95.
3.   

msc-hmn:fbr 60 mg/L

   MUREAV    Mutation Research. 121 (1983),71.
4.   

dnd-rat:lvr 30 µmol/L

   SinJF#    Personal Communication from J.F. Sina, Merck Institute for Therapeutic Research, West Point, PA 19486, to the Editor of RTECS, Cincinnati, OH, on October 26, 1982
5.   

dns-mus-orl 200 mg/kg

   MUREAV    Mutation Research. 125 (1984),291.
6.   

orl-rat LD50:500 mg/kg

   JIHTAB    Journal of Industrial Hygiene and Toxicology. 29 (1947),1.
7.   

orl-mus TD:5460 µg/kg

   EJCODS    European Journal of Cancer and Clinical Oncology. 21 (1985),865.
8.   

orl-rat LD50:500 mg/kg

   JIHTAB    Journal of Industrial Hygiene and Toxicology. 29 (1947),1.
9.   

orl-mus LD50:205 mg/kg

   EJCODS    European Journal of Cancer and Clinical Oncology. 21 (1985),865.
10.   

ipr-mus LDLo:250 mg/kg

   CBCCT*    “Summary Tables of Biological Tests” Na

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 91.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 (1972),p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 (1972),p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 28 (1982),p. 151.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.

Safety Profile

Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion and intraperitoneal routes. Human mutation data reported. An irritant. Effects resemble those of benzidine. See also BENZIDINE. Slight to moderate fire hazard when exposed to heat, flames (sparks), or powerful oxidizers. To fight fire, use water spray, mist, dry chemical. When heated to decomposition it emits toxic fumes of NOx. See also AROMATIC AMINES.
The Hazard Codes of 4-AMINODIPHENYL(92-67-1):   T,  Xn
HazardClass: 6.1(a)
The Risk Statements information of 4-AMINODIPHENYL(92-67-1):
22:  Harmful if swallowed 
45:  May cause cancer 
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed 
36/37/38:  Irritating to eyes, respiratory system and skin 
The Safety Statements information of 4-AMINODIPHENYL(92-67-1):
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
53:  Avoid exposure - obtain special instruction before use 
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: DU8925000
PackingGroup: I

Standards and Recommendations

OSHA PEL: Cancer Suspect Agent
ACGIH TLV: Confirmed Human Carcinogen
DFG MAK: Human Carcinogen