CAS No.926-02-3,TERT-BUTYL VINYL ETHER Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	926-02-3
Name:	TERT-BUTYL VINYL ETHER
Article Data:	14

Formula:	C₆H₁₂O
Molecular Weight:	100.161
Synonyms:	Ether,tert-butyl vinyl (6CI,7CI,8CI);2-(Ethenyloxy)-2-methylpropane;t-Butyl vinylether;tert-Butoxyethylene;tert-Butyl vinyl ether;2-Methyl-2-(vinyloxy)propane;
EINECS:	618-860-6
Density:	0.775 g/cm³
Melting Point:	75-76 °C(lit.)
Boiling Point:	75 °C at 760 mmHg
Flash Point:	-17oC (closedoCup)
Solubility:	Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
Appearance:	liquid
Hazard Symbols:	Xi; F
Risk Codes:	11-38
Safety:	16-26-36
Transport Information:	UN 3271 3/PG 2
PSA:	9.23000
LogP:	1.94500

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Specification

The CAS registry number of Propane,2-(ethenyloxy)-2-methyl- is 926-02-3. The systematic name is tert-butyl ethenyl ether. In addition, the molecular formula is C₆H₁₂O and the molecular weight is 100.16. It is a kind of liquid and belongs to the classes of Monomers; Polymer Science; Vinyl Ethers. It should be stored in a cool and dry place.

Physical properties about Propane,2-(ethenyloxy)-2-methyl- are: (1)ACD/LogP: 1.74; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.74; (4)ACD/LogD (pH 7.4): 1.74; (5)ACD/BCF (pH 5.5): 12.3; (6)ACD/BCF (pH 7.4): 12.3; (7)ACD/KOC (pH 5.5): 209.83; (8)ACD/KOC (pH 7.4): 209.83; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 9.23 Å²; (13)Index of Refraction: 1.399; (14)Molar Refractivity: 31.28 cm³; (15)Molar Volume: 129 cm³; (16)Polarizability: 12.4×10^-24cm³; (17)Surface Tension: 20.4 dyne/cm; (18)Density: 0.775 g/cm³; (19)Enthalpy of Vaporization: 30.31 kJ/mol; (20)Boiling Point: 75 °C at 760 mmHg; (21)Vapour Pressure: 117 mmHg at 25°C.

Preparation of Propane,2-(ethenyloxy)-2-methyl-: it can be prepared by (2-chloro-ethoxy)-ethene and 2-methyl-propan-2-ol. This reaction will need reagent Hg(OAc)₂. The yield is about 95%.

Uses of Propane,2-(ethenyloxy)-2-methyl-: It can react with ketene to produce 3-tert-Butoxycyclobutanone. This reaction will need reagent ZnCl₂and solvent acetonitrile. And the yield is about 92%.

Propane,2-(ethenyloxy)-2-methyl- can react with ketene to produce 3-tert-Butoxycyclobutanone

When you are using this chemical, please be cautious about it as the following:
It is a kind of highly flammable chemical which irritates to skin. During using it, you should wear suitable protective clothing. And keep away from sources of ignition-No smoking. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O(\C=C)C(C)(C)C
(2)InChI: InChI=1/C6H12O/c1-5-7-6(2,3)4/h5H,1H2,2-4H3
(3)InChIKey: PGYJSURPYAAOMM-UHFFFAOYAB