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| CAS No.: | 97-44-9 |
|---|---|
| Name: | ACETARSONE |
| Molecular Structure: | |
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| Formula: | C8H10 As N O5 |
| Molecular Weight: | 275.093 |
| Synonyms: | Arsonicacid, [3-(acetylamino)-4-hydroxyphenyl]- (9CI); m-Arsanilic acid,N-acetyl-4-hydroxy- (7CI,8CI); 190F; 3-Acetamido-4-hydroxybenzenearsonic acid;3-Acetamido-4-hydroxyphenylarsonic acid;3-Acetylamino-4-hydroxyphenyl-1-arsonic acid;3-Acetylamino-4-hydroxyphenylarsonic acid; Acetarsol; Acetarsone;Acetphenarsine; Amarsan; Amoebal; Arsaphen; Arsonine; Chrlich 594; Devegan;Disparicida; Dynarsan; Ehrlich 594; F 190; Fourneau 190; Ginarsol; Goyl;Gynoplix; Kharophen; Kubarsol; Limarsol; Malagride; Mexyl; Monargan;N-Acetyl-4-hydroxy-m-arsanilic acid; NSC 13160; NSC 3247; Nilacid; Oralcid;Orarsan; Osarsal; Osarsol; Osarsole; Osvarsan; Pallicid; Paroxyl; SVC; Sanogyl;Spirocid; Spirozid; Stovarsol; Stovarsolan; Vagisept; Vagoflor |
| Density: | g/cm3 |
| Melting Point: | 220.5°C |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Hazard Symbols: |
 
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| Risk Codes: | 23/25-50/53 |
| Safety: | Poison by ingestion and intravenous routes. Human systemic effects by ingestion: respiratory system, endocrine system, dermatitis, and fever. Human systemic effects by intravaginal route: hallucinations, distorted perceptions, convulsions, nausea or vomiting, decreased urine volume, and fever. Mutation data reported. See also ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of NOx and As. |
| PSA: | 106.86000 |
| LogP: | -1.01540 |
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Chemistry
Empirical Formula of Acetarsone (CAS NO.97-44-9): C8H10AsNO5
Molecular Weight: 275.0903 g/mol
EINECS: 202-582-3
Structure of Acetarsone (CAS NO.97-44-9):
IUPAC Name: (3-Acetamido-4-hydroxyphenyl)arsonic acid
Canonical SMILES: CC(=O)NC1=C(C=CC(=C1)[As](=O)(O)O)O
InChI: InChI=1S/C8H10AsNO5/c1-5(11)10-7-4-6(9(13,14)15)2-3-8(7)12/h2-4,12H,1H3,(H,10,11)(H2,13,14,15)
InChIKey: ODFJOVXVLFUVNQ-UHFFFAOYSA-N
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | oral | 150mg/kg (150mg/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Proceedings of the Society for Experimental Biology and Medicine. Vol. 27, Pg. 267, 1930. |
| man | TDLo | oral | 89mg/kg/9D (89mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES ENDOCRINE: OTHER CHANGES SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE" | American Journal of the Medical Sciences. Vol. 174, Pg. 819, 1927. |
| mouse | LD50 | intravenous | 180mg/kg (180mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03309, | |
| mouse | LD50 | oral | 4mg/kg (4mg/kg) | Compilation of LD50 Values of New Drugs. | |
| rabbit | LDLo | intravenous | 120mg/kg (120mg/kg) | Archives of Dermatology and Syphilology. Vol. 25, Pg. 799, 1932. | |
| rabbit | LDLo | oral | 125mg/kg (125mg/kg) | SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Proceedings of the Society for Experimental Biology and Medicine. Vol. 27, Pg. 267, 1930. |
| rat | LDLo | intravenous | 300mg/kg (300mg/kg) | Archives of Dermatology and Syphilology. Vol. 25, Pg. 799, 1932. | |
| rat | LDLo | oral | 1200mg/kg (1200mg/kg) | British Journal of Pharmacology and Chemotherapy. Vol. 3, Pg. 44, 1948. | |
| women | LDLo | intravaginal | 155mg/kg/2D-I (155mg/kg) | BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" GASTROINTESTINAL: NAUSEA OR VOMITING | British Medical Journal. Vol. 1, Pg. 1282, 1961. |
| women | LDLo | intravaginal | 1576mg/kg/2D- (1576mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: NAUSEA OR VOMITING KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED | British Medical Journal. Vol. 2, Pg. 242, 1960. |
| women | TDLo | oral | 86mg/kg/8D (86mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE" | American Journal of the Medical Sciences. Vol. 174, Pg. 819, 1927. |
Consensus Reports
ARSENIC and its compounds are on the Community Right-To-Know List.
Safety Profile
Poison by ingestion and intravenous routes. Human systemic effects by ingestion: respiratory system, endocrine system, dermatitis, and fever. Human systemic effects by intravaginal route: hallucinations, distorted perceptions, convulsions, nausea or vomiting, decreased urine volume, and fever. Mutation data reported. See also ARSENIC COMPOUNDS. When heated to decomposition it emits very toxic fumes of NOx and As.
Hazard Codes of Acetarsone (CAS NO.97-44-9): 
T,
N
Risk Statements: 23/25-50/53
R23/25:Toxic by inhalation and if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 20/21-28-45-60-61
S20:When using, do not eat or drink.
S21:When using do not smoke.
S28:After contact with skin, wash immediately with plenty of soap-suds.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
Standards and Recommendations
OSHA PEL: TWA 500 µg(As)/m3
ACGIH TLV: BEI: 35 μ (As)/L inorganic ARSENIC and methylated metabolites in urine
Specification
Acetarsone , its cas register number is 97-44-9. It also can be called Acid Leather Acetarsol ; Acetamino-hydroxyphenyl-arsonsaeure ; and 3-Acetamido-4-hydroxy-phenylarsonic acid .