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Basic Information
CAS No.: 99-06-9
Name: m-Salicylic acid
Molecular Structure:
Molecular Structure of 99-06-9 (m-Salicylic acid)
Formula: C7H6O3
Molecular Weight: 138.123
Synonyms: Benzoicacid, m-hydroxy- (8CI);3-Carboxyphenol;
EINECS: 202-726-5
Density: 1.375 g/cm3
Melting Point: 201 °C
Boiling Point: 346.1 °C at 760 mmHg
Flash Point: 177.3 °C
Solubility: slightly soluble in water
Appearance: white to light yellow crystal powder
Hazard Symbols: HarmfulXn,IrritantXi
Risk Codes: 22-36/37/38
Safety: 26-36/37/39
PSA: 57.53000
LogP: 1.09040
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    3-Hydroxybenzoic acid

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    3-Hydroxybenzoic acid

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    Product Name: 3-Hydroxybenzoic acid Synonyms: kyselina3-hydroxybenzoova;meta-Hydroxybenzoic acid;m-Hba;m-hydroxy-benzoicaci;m-Salicylic acid;m-salicylicacid;m-Hydroxybenzoic Acid 3-Hydroxybenzoic Acid;m-HydroxybenzoicacidM-HydroxybenzoicAcid C

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    m-hydroxybenzoic acid

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    m-Salicylic acid

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Chemistry

IUPAC Name: 3-Hydroxybenzoic acid
Synonyms of 3-Hydroxybenzoic acid (CAS NO.99-06-9): 3-Carboxyphenol ; Acido m-idrossibenzoico ; Kyselina 3-hydroxybenzoova ; m-Hydroxybenzoic acid ; m-Salicylic acid
CAS NO: 99-06-9
Molecular Formula: C7H6O3
Molecular Weight: 138.12
Molecular Structure:
EINECS: 202-726-5
Melting Point: 201 °C
Boiling Point: 346.1 °C at 760 mmHg 
Flash Point: 177.3 °C
Index of Refraction: 1.615 
Molar Refractivity: 35.06 cm
Molar Volume: 100.3 cm3 
Surface Tension: 64.4 dyne/cm 
Density: 1.375 g/cm3  
Enthalpy of Vaporization: 62.29 kJ/mol 
Vapour Pressure: 2.24E-05 mmHg at 25°C 
Water Solubility: slightly soluble
Appearance: white to light yellow crystal powder
Product Categories of 3-Hydroxybenzoic acid (CAS NO.99-06-9): Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;pharmacetical;Benzoic acid;C7;Carbonyl Compounds;Carboxylic Acids

Uses

 3-Hydroxybenzoic acid (CAS NO.99-06-9) can be used as the object fungicides, preservatives, plasticizers and pharmaceutical intermediates.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2gm/kg (2000mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 19, Pg. 483, 1946.
rat LD50 intraperitoneal 3700mg/kg (3700mg/kg)   Bollettino Chimico Farmaceutico. Vol. 112, Pg. 53, 1973.
 

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information about 3-Hydroxybenzoic acid (CAS NO.99-06-9):
Hazard Codes: HarmfulXnXi
Risk Statements: 22-36/37/38 
R22: Harmful if swallowed. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 3
RTECS: DH1924980
Hazard Note: Irritant
HS Code: 29182990
Moderately toxic by ingestion and intraperitoneal routes. An experimental teratogen. When heated to decomposition it emits acrid smoke and fumes.

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dangerous fire hazard in the form of dust when exposed to heat or flame.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.