10175-53-8Relevant articles and documents
Phosphoramidite complexes of Pd(II), Pt(II) and Rh(I): An effective hydrosilylation catalyst of 1-hexyne and 1-octene
Carroll, Hannah K.,Parlane, Fraser G.L.,Reich, Noah,Jelier, Benson J.,Montgomery, Craig D.
, p. 78 - 83 (2017/06/13)
The hydrophosphorane HP(OC6H4NMe)2 was used to prepare the diastereotopic complexes [MCl2{P(OC6H4NMe)OC6H4NHMe}] (M?=?Pd, Pt) by reaction with [MCl2(PhCN)2], and [RhCl(PPh3){P(OC6H4NMe)OC6H4NHMe}] by reaction with [RhCl(PPh3)3]. To form these complexes, the phosphorane undergoes ring-opening, whereby it is coordinated as the tautomeric neutral phosphoramidite-amino chelating ligand. The crystal structure of [RhCl(PPh3){P(OC6H4NMe)OC6H4NHMe}] was determined and the geometry about the Rh(I) atom is square-planar with cis-disposed phosphorus-donor ligands. The Rh–P distance is shortened (2.1056(6) ?) due to Rh(d)?→?P π-backbonding. In addition, [RhCl(PPh3){P(OC6H4NMe)OC6H4NHMe}] was shown to be an effective regio- and stereoselective catalyst for the hydrosilylation of 1-octene and 1-hexyne.
Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes
Jiang, Yanfeng,Blacque, Olivier,Fox, Thomas,Freeh, Christian M.,Berke, Heinz
experimental part, p. 2121 - 2128 (2009/09/30)
Rhenium(I) complexes of type [ReBr2(L)(NO)(PR3) 2] (L = H2 (1), CH3CN (2), and ethylene (3); R = iPr (a) and cyclohexyl (Cy; b)) catalyze dehydrogenative silylation of alkenes in a highly selective ma