105751-13-1

• 

• Basic information

  1. Product Name: FMOC-SER(TBU)-OPFP
  2. Synonyms: N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-O-T-BUTYL-L-SERINE PENTAFLUORPHENOL ESTER;FMOC-SER(TBU)-OPFP;FMOC-SERINE(TBU)-OPFP;FMOC-L-SER(TBU)-OPFP;FMOC-O-TERT-BUTYL-L-SERINE PENTAFLUOROPHENYL ESTER;FMOC-O-T-BUTYL-L-SERINE PENTAFLUOROPHENYL ESTER;FMOC-O-TERT-BUTYL-L-SERINE PENTAFLUORO-PHENYL ESTER, TECHN 90+% (HPLC);(S)-perfluorophenyl 2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-3-tert-butoxypropanoate
  3. CAS NO:105751-13-1
  4. Molecular Formula: C₂₈H₂₄F₅NO₅
  5. Molecular Weight: 549.49
  6. EINECS: N/A
  7. Product Categories: Fmoc-Amino Acids and Derivatives;Fmoc-Amino acid series
  8. Mol File: 105751-13-1.mol
  9. Article Data: 3

• Chemical Properties

  1. Melting Point: 67-71℃
  2. Boiling Point: 628.165 °C at 760 mmHg
  3. Flash Point: 333.702 °C
  4. Appearance: /
  5. Density: 1.35 g/cm³
  6. Vapor Pressure: 1.08E-15mmHg at 25°C
  7. Refractive Index: 1.545
  8. Storage Temp.: 2-8°C
  9. Solubility: N/A
  10. PKA: 9.82±0.46(Predicted)
  11. CAS DataBase Reference: FMOC-SER(TBU)-OPFP(CAS DataBase Reference)
  12. NIST Chemistry Reference: FMOC-SER(TBU)-OPFP(105751-13-1)
  13. EPA Substance Registry System: FMOC-SER(TBU)-OPFP(105751-13-1)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany: 3
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 105751-13-1(Hazardous Substances Data)

• Suppliers
• Usage
• SDS
• Upstream product
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105751-13-1 Suppliers

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• N-9-Fluorenylmethoxycarbonyl-O-tert-butylserine pentafluorophenyl ester

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• Dayang Chem (Hangzhou) Co.,Ltd.
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• L-Serine,O-(1,1-dimethylethyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-,2,3,4,5,6-pentafluorophenyl ester

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• Hangzhou J&H Chemical Co., Ltd.
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• L-Serine,O-(1,1-dimethylethyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-,2,3,4,5,6-pentafluorophenyl ester

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• 10 Gram

• 500 Kilogram/Month

• Zibo Hangyu Biotechnology Development Co., Ltd
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• Fmoc-Ser(tBu)-OPfp

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• 1 Milligram

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• Xiamen Jenny Chemical Technology Co., Ltd.
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• FMOC-SER(TBU)-OPFP

  Cas No: 105751-13-1

• USD $ 2.0-2.0 / Kilogram

• 1 Kilogram

• 10000000 Kilogram/Year

• TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD
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• N-9-Fluorenylmethoxycarbonyl-O-tert-butylserine pentafluorophenyl ester

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• Suzhou Health Chemicals Co., Ltd.
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• L-Serine,O-(1,1-dimethylethyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]-,2,3,4,5,6-pentafluorophenyl ester

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• Research Peptide Biotechnology Co., Ltd.
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• FMOC-SER(TBU)-OPFP

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• Henan Allgreen Chemical Co.,Ltd
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105751-13-1 Usage

Uses

Fmoc-Ser(tBu)-OPfp is used as a reactant in the synthesis of peptides and peptide derivatives.

Check Digit Verification of cas no

The CAS Registry Mumber 105751-13-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,7,5 and 1 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 105751-13:
(8*1)+(7*0)+(6*5)+(5*7)+(4*5)+(3*1)+(2*1)+(1*3)=101
101 % 10 = 1
So 105751-13-1 is a valid CAS Registry Number.

InChI:InChI=1/C28H24F5NO5/c1-28(2,3)38-13-19(26(35)39-25-23(32)21(30)20(29)22(31)24(25)33)34-27(36)37-12-18-16-10-6-4-8-14(16)15-9-5-7-11-17(15)18/h4-11,18-19H,12-13H2,1-3H3,(H,34,36)/t19-/m0/s1

105751-13-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name	Fmoc-Ser(tBu)-OPfp

1.2 Other means of identification

Product number	-
Other names	(2,3,4,5,6-pentafluorophenyl) (2S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-[(2-methylpropan-2-yl)oxy]propanoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:105751-13-1 SDS

105751-13-1Upstream product

• 18822-58-7 (S)-O-tert-butylserine 
• 88744-04-1 (9-fluorenyl)methyl pentafluorophenyl carbonate 
• 71989-33-8 Fmoc-Ser(tBu)-OH 
• 244633-31-6 pentafluorophenyl 4-nitrobenzenesulfonate 
• 771-61-9 2,3,4,5,6-pentafluorophenol 

105751-13-1Downstream Products

• 1334511-57-7 N-(9-fluorenylmethoxycarbonyl)-O⁽³⁾-tert-butyl-L-seryl-N-ethyl-S-triphenylmethyl-L-cysteine 
• 160410-55-9 N^α-(fluoren-9-ylmethoxycarbonyl)-O-(3,4,6-tri-O-acetyl-2-allyloxycarbonylamino-2-deoxy-β-D-glucopyranosyl)-L-serine pentafluorophenyl ester 
• 160410-57-1 O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-N^α-(fluoren-9-ylmethoxycarbonyl)-L-serine pentafluorophenyl ester 
• 141462-11-5 N^α-(9H-fluoren-9-yl)methoxycarbonyl-O-(3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-galactopyranosyl)-L-serine pentafluorophenyl ester 
• 129398-80-7 Fmoc--Ser-O-Pfp 
• 86061-05-4 N^α-(fluoren-9-ylmethoxycarbonyl)-L-serine pentafluorophenyl ester 

105751-13-1Relevant articles and documents

New solid support for the synthesis of 3′-oligonucleotide conjugates through glyoxylic oxime bond formation

Spinelli, Nicolas,Edupuganti, Om Prakash,Defrancq, Eric,Dumy, Pascal

, p. 219 - 222 (2007)

(Chemical Equation Presented) A novel solid support 1 was synthesized to incorporate glyoxylic aldehyde functionality at the oligonucleotide 3′-terminus. 6-mer and 11-mer oligonucleotide sequences containing 3′-glyoxylic aldehyde functionality were prepar

9-Fluorenylmethyl Pentafluorophenyl Carbonate as a Useful Reagent for the Preparation of N-9-Fluorenylmethyloxycarbonylamino Acids and their Pentafluorophenyl Esters

Schoen, Istvan,Kisfaludy, Lajos

, p. 303 - 305 (2007/10/02)

9-Fluorenylmethyl pentafluorophenyl carbonate is a useful reagent for the efficient, side reaction-free introduction of N-9-fluorenylmethyloxycarbonyl protecting group into amino acids and for the subsequent preparation of their pentafluorophenyl esters.Some new compounds of both types are described.

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