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13066-51-8

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13066-51-8 Usage

Synthesis Reference(s)

Tetrahedron Letters, 15, p. 2215, 1974 DOI: 10.1016/S0040-4039(01)93180-6

Check Digit Verification of cas no

The CAS Registry Mumber 13066-51-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,6 and 6 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 13066-51:
(7*1)+(6*3)+(5*0)+(4*6)+(3*6)+(2*5)+(1*1)=78
78 % 10 = 8
So 13066-51-8 is a valid CAS Registry Number.

13066-51-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 7-methyl-3-methylideneoct-6-en-1-ol

1.2 Other means of identification

Product number -
Other names 7-methyl-3-methylene-6-octen-1-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13066-51-8 SDS

13066-51-8Relevant articles and documents

Studies on the alkylation of 3-methyl-3-buten-1-ol dianion: An efficient synthesis of 3-methylene-1-alkanols including a San Jose scale sex pheromone

Yong, Kelvin H.,Lotoski, John A.,Chong, J. Michael

, p. 8248 - 8251 (2001)

-

-

Alexakis,A. et al.

, p. 471 - 485 (1975)

-

Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes

Liu, Yangbin,Fiorito, Daniele,Mazet, Clément

, p. 5284 - 5288 (2018/06/21)

A highly enantioselective Cu-catalyzed borylation of 2-substituted 1,3-dienes is reported. The use of a chiral phosphanamine ligand is essential in achieving high chemo-, regio-, diastereo- and enantioselectivity. It provides access to a variety of homoallylic boronates in consistently high yield and enantiomeric excess with 2-aryl and 2-heteroaryl 1,3-dienes as well as sterically demanding 2-alkyl 1,3-dienes. Preliminary investigations based on a non-linear effect study point to a mechanism involving more than one metal center.

Chelation versus Non-Chelation Control in the Stereoselective Alkenyl sp2 C?H Bond Functionalization Reaction

Liang, Qiu-Ju,Yang, Chao,Meng, Fei-Fan,Jiang, Bing,Xu, Yun-He,Loh, Teck-Peng

supporting information, p. 5091 - 5095 (2017/04/24)

A hydroxy group chelation-assisted stereospecific oxidative cross-coupling reaction between alkenes was developed under mild reaction conditions. In the presence of palladium catalyst, the alkenes tethered with hydroxy functionality can couple efficiently with electron-deficient alkenes to form the corresponding multi-substituted olefin products. The hydroxy group on the substrate could play dual roles in reaction, acting as the directing group for alkenyl C?H bond activation and controlling the stereoselectivity of the products.

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