13071-88-0Relevant articles and documents
REACTION OF HALOOLEFINS WITH NITRONIUM TETRAFLUOROBORATE
Talybov, A. G.,Mursakulov, I. G.,Guseinov, M. M.,Smit, V. A.
, p. 581 - 584 (1982)
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Synthese von α-Fluoracrylsaeure und Derivaten
Gassen, K.-R.,Bielefeldt, D.,Marhold, A.,Andres P.
, p. 149 - 162 (2007/10/02)
Three new routes to derivatives of α-fluoracrylic acid, including a laboratory synthesis and a large-scale method, are reported.The processes are (i) addition of elementary fluorine to acrylic esters and subsequent elimination of HF; (ii) addition of difluorocarbene to isopropenyl methyl ether, oxidation via ring opening and dehalogenation; and (iii) "nitrofluorination" of 2,3-dichloropropene, hydrolysis and dechlorination.