138500-86-4Relevant articles and documents
Recyclable Pd2dba3/XPhos/PEG-2000 System for Efficient Borylation of Aryl Chlorides: Practical Access to Aryl Boronates
Cai, Mingzhong,Huang, Bin,Luo, Chengkai,Xu, Caifeng
, (2021/12/02)
Pd2dba3/XPhos in poly(ethylene glycol) (PEG-2000) is shown to be a highly stable and efficient catalyst for the borylation of aryl chlorides with bis(pinacolato)diboron. The borylation reaction proceeds smoothly at 110 °C, delivering a wide variety of aryl boronates in good to excellent yields with high functional group tolerance. The crude products were easily isolated via simple extraction of the reaction mixture with cyclohexane. Moreover, both expensive Pd2dba3 and XPhos in PEG-2000 system could be readily recycled and reused more than six times without loss of catalytic efficiency.
Sulfonamide derivatives
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Page 23, (2010/02/05)
The present invention provides certain sulfonamide derivatives useful for potentiating glutamate receptor function in a patient and therefore, useful for treating a wide variety of conditions, such as psychiatric and neurological disorders.
SYNTHESES OF SOME ISOTHIOCYANATOPHENYLBORONIC ACIDS
Ramalingam, Kondareddiar,Nowotnik, David P.
, p. 729 - 734 (2007/10/03)
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