138517-66-5 Usage
Uses
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant: To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine. To prepare porous organic imine cages by cycloimination reaction with triformylbenzene. To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.
Check Digit Verification of cas no
The CAS Registry Mumber 138517-66-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,8,5,1 and 7 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 138517-66:
(8*1)+(7*3)+(6*8)+(5*5)+(4*1)+(3*7)+(2*6)+(1*6)=145
145 % 10 = 5
So 138517-66-5 is a valid CAS Registry Number.
InChI:InChI=1/C16H16N2/c17-15-13-9-5-1-2-6-10(9)14(16(15)18)12-8-4-3-7-11(12)13/h1-8,13-16H,17-18H2/t13?,14?,15-,16-/m0/s1
138517-66-5Relevant articles and documents
Total Synthesis of (-)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane
Coffinier, Romain,Assal, Mourad El,Peixoto, Philippe A.,Bosset, Cyril,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Pouységu, Laurent,Quideau, Stéphane
, p. 1120 - 1123 (2016)
The first total and biomimetic synthesis of the natural bis(sesquiterpene) (-)-bacchopetiolone (revised structure) was completed through a highly diastereoselective hydroxylative phenol dearomatization/[4+2]-dimerization cascade conversion of (+)-curcuphe
A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations
Trost, Barry M.,Van Vranken, David L.,Bingel, Carsten
, p. 9327 - 9343 (2007/10/02)
A new class of ligands for asymmetric transition metal catalysis based on 2-(diphenylphosphino)benzoic acid was used in a mechanistically-defined palladium-catalyzed reaction in which enantiodifferentiation was the result of selective ionization of substr