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14163-00-9

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14163-00-9 Usage

Description

4-NITRO-2,2'-BIPYRIDINE-N-OXIDE is a chemical compound characterized by its molecular formula C10H7N3O3. It is a nitro derivative of bipyridine, known for its pale yellow solid appearance and its solubility in organic solvents rather than water. 4-NITRO-2,2'-BIPYRIDINE-N-OXIDE plays a significant role in coordination chemistry, particularly as a ligand for the formation of coordination compounds with transition metals.

Uses

Used in Coordination Chemistry:
4-NITRO-2,2'-BIPYRIDINE-N-OXIDE is used as a ligand for the synthesis of coordination compounds with transition metals. Its ability to chelate with metal ions is valuable for creating stable complexes that are applicable in various fields.
Used in Catalysis:
In the field of catalysis, 4-NITRO-2,2'-BIPYRIDINE-N-OXIDE-based coordination compounds are utilized to facilitate chemical reactions, enhancing their efficiency and selectivity.
Used in Material Science:
4-NITRO-2,2'-BIPYRIDINE-N-OXIDE contributes to the development of new materials with unique properties, such as those used in sensors, electronic devices, and advanced coatings, by participating in the formation of metal-organic frameworks or other composites.
Used as a Precursor in Organic Synthesis:
4-NITRO-2,2'-BIPYRIDINE-N-OXIDE is used as a precursor in the synthesis of dyes, pharmaceuticals, and other heterocyclic compounds due to the reactivity of its nitro group, which can be reduced or undergo other transformations.
Used in Organic Light-Emitting Diodes (OLEDs):
4-NITRO-2,2'-BIPYRIDINE-N-OXIDE has been studied for its potential use in OLEDs, capitalizing on its electronic properties to improve the performance of these devices, such as enhancing their brightness, efficiency, and stability.
Used in Research and Development:
4-NITRO-2,2'-BIPYRIDINE-N-OXIDE is also utilized in academic and industrial research settings to explore new applications and properties, further expanding its use in science and technology.

Check Digit Verification of cas no

The CAS Registry Mumber 14163-00-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,1,6 and 3 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 14163-00:
(7*1)+(6*4)+(5*1)+(4*6)+(3*3)+(2*0)+(1*0)=69
69 % 10 = 9
So 14163-00-9 is a valid CAS Registry Number.
InChI:InChI=1/C10H7N3O3/c14-12-6-4-8(13(15)16)7-10(12)9-3-1-2-5-11-9/h1-7H

14163-00-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-nitro-1-oxido-2-pyridin-2-ylpyridin-1-ium

1.2 Other means of identification

Product number -
Other names 4-nitro-2,2'-bipyridyl-1-oxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14163-00-9 SDS

14163-00-9Relevant articles and documents

Electrocatalytic Biosynthesis using a Bucky Paper Functionalized by [Cp*Rh(bpy)Cl]+ and a Renewable Enzymatic Layer

Zhang, Lin,Etienne, Mathieu,Vilà, Neus,Le, Thi Xuan Huong,Kohring, Gert-Wieland,Walcarius, Alain

, p. 4067 - 4073 (2018)

A bioelectrode for electroenzymatic synthesis was prepared, combining a layer for NADH regeneration and a renewable layer for enzymatic substrate reduction. The covalent immobilization of a rhodium complex mediator ([Cp*Rh(bpy)Cl]+) on the surface of a bucky paper electrode was achieved by following an original protocol in two steps. A bipyridine ligand was first grafted on the electrode by electro-reduction of bipyridyl diazonium cations generated from 4-amino-2,2′-bipyridine, and the complex was then formed by reaction with [RhCp*Cl2]2. A turnover frequency of 1.3 s?1 was estimated for the electrocatalytic regeneration of NADH by this immobilized complex, with a Faraday efficiency of 83 %. The bucky paper electrode was then overcoated by a bio-doped porous layer made of glassy fibers with immobilized D-sorbitol dehydrogenase. This assembly allowed for the efficient separation of the enzyme and the rhodium catalyst, which is a prerequisite for effective bioelectrocatalysis with such bioelectrochemical system, while allowing effective mass transport of NAD+/NADH cofactor from one layer to the other. Thereby, it was possible to reuse the same mediator-functionalized bucky paper with three different enzyme layers. The bioelectrode was applied to the electroenzymatic reduction of D-fructose to D-sorbitol. A turnover frequency of 0.19 s?1 for the rhodium complex was observed in the presence of 3 mM D-fructose and a total turnover number higher than 12000 was estimated.

Process development of a potent neuroprotector agent: Collismycin A

Lopez-Ogalla, Javier,Saiz, Gonzalo,Palomo, Francisco E.

, p. 120 - 126 (2013)

An efficient synthetic process for the natural product of marine origin, collismycin type A, a potent neuroprotector agent, has been developed. This new synthetic route avoids chromatographic steps, implies an improvement cost, and provides easy access to large scale.

Recyclable Transition Metal Catalysis using Bipyridine-Functionalized SBA-15 by Co-condensation of Methallylsilane with TEOS

Han, Ye Ri,Kim, Jae Soon,Park, Woo-Jin,Lee, Chang-Hee,Cheon, Jinwoo,Jun, Chul-Ho

, p. 197 - 201 (2021/01/18)

Well-defined recyclable Pd- and Rh-bipyridyl group-impregnated SBA-15 catalysts were prepared for C?C bond coupling reaction and selective hydrogenation reactions, respectively. These SBA-15 derived ligands for the catalysts were prepared by direct and indirect co-condensation method using bipyridyl-linked methallylsilane. This indirect method, involving methoxysilane generated from methallylsilane shows higher loading efficiency of transition metal catalysts on SBA-15 than the direct use of methallylsilane.

Synthesis and characterization of a new ditopic bipyridine-terpyridine bridging ligand using a Suzuki cross-coupling reaction

Zibaseresht, Ramin

, p. 277 - 287 (2020/02/13)

Synthesis of a new bridging ligand 4'-{4-[(2,2'-bipyridin)-4-yl]-phenyl}-2,2':6'-2''-terpyridine (I) was reported. A Suzuki cross-coupling reaction was conducted for the preparation of such ligand in two different routes either between 4'-(4-bromophenyl)-2,2':6'-2''-terpyridine and 2,2'-bipyridyl-4-boronic acid or 4'-(4-boronatophenyl)-2,2':6',2''-terpyridine and 4-bromo-2,2'-bipyridine. Br HO OH B + N N N N N N N HO OH B Br N + N N N (I) N N N N

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