16854-32-3

• 

• Basic information

  1. Product Name: (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL
  2. Synonyms: 2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol;L-THIOMICAMINE;(1S,2S)-(+)-THIOMICAMINE;(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL;[S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol;thiomicamine;(1S,2S)-1-[4-(Methylthio)phenyl]-2-amino-1,3-propanediol;(1S,2S)-1-[4-(Methylthio)phenyl]-2-aminopropane-1,3-diol
  3. CAS NO:16854-32-3
  4. Molecular Formula: C₁₀H₁₅NO₂S
  5. Molecular Weight: 213.3
  6. EINECS: 240-878-4
  7. Product Categories: N/A
  8. Mol File: 16854-32-3.mol
  9. Article Data: 2

• Chemical Properties

  1. Melting Point: 151-154 °C(lit.)
  2. Boiling Point: 428.2°Cat760mmHg
  3. Flash Point: 212.8°C
  4. Appearance: /
  5. Density: 1.25g/cm³
  6. Vapor Pressure: 4.29E-08mmHg at 25°C
  7. Refractive Index: 1.624
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. PKA: 11.75±0.45(Predicted)
  11. CAS DataBase Reference: (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(CAS DataBase Reference)
  12. NIST Chemistry Reference: (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(16854-32-3)
  13. EPA Substance Registry System: (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL(16854-32-3)

• Safety Data

  1. Hazard Codes: Xi
  2. Statements: 36/37/38
  3. Safety Statements: 26-37/39
  4. WGK Germany: 3
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 16854-32-3(Hazardous Substances Data)

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16854-32-3 Suppliers

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• High quality L-Thiomicamine with high purity

  Cas No: 16854-32-3

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• 1 Kilogram

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• Simagchem Corporation
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• (1S,2S)-(+)-2-amino-1-[4-(methylthio)phenyl]-1,3-propanediol

  Cas No: 16854-32-3

• USD $ 3.0-3.0 / Kilogram

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• Dayang Chem (Hangzhou) Co.,Ltd.
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• Manufacturer supply CAS 16854-32-3 with best quality

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• USD $ 139.0-210.0 / Kilogram

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• Zhuozhou Wenxi import and Export Co., Ltd
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• (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL 16854-32-3

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• USD $ 38.0-59.0 / Kilogram

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• Hebei Sankai Chemical Technology Co., Ltd
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• L-Thiomicamine

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• Xiamen Hisunny Chemical Co.,Ltd
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• 1,3-Propanediol,2-amino-1-[4-(methylthio)phenyl]-, (1S,2S)-

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• Hangzhou J&H Chemical Co., Ltd.
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• 1,3-Propanediol,2-amino-1-[4-(methylthio)phenyl]-, (1S,2S)-

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• Zibo Hangyu Biotechnology Development Co., Ltd
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• (1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

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• Henan Allgreen Chemical Co.,Ltd
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• L-Thiomicamine

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• Aecochem Corp.
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• (1S,2S)-(+)-2-Amino-1-[4-(methylthio)phenyl]-1,3-propanediol

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16854-32-3 Usage

Uses

(1S,2S)-(+)-Thiomicamine can be used:As a starting material in the synthesis of 3,4-dihydroisoquinolinium salts, which are employed as promoters in asymmetric epoxidation and oxidation?reactions.As a starting material in the synthesis of an α-amino acid named (3R,4R)-4-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid, which is used to prepare modified peptides of biological importance.As a chiral base in the resolution of an angiotensin II type 2 receptor [AT2R] antagonist named EMA401.

Check Digit Verification of cas no

The CAS Registry Mumber 16854-32-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,8,5 and 4 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 16854-32:
(7*1)+(6*6)+(5*8)+(4*5)+(3*4)+(2*3)+(1*2)=123
123 % 10 = 3
So 16854-32-3 is a valid CAS Registry Number.

InChI:InChI=1/C10H15NO2S/c1-14-8-4-2-7(3-5-8)10(13)9(11)6-12/h2-5,9-10,12-13H,6,11H2,1H3/t9-,10-/m0/s1

16854-32-3 Well-known Company Product Price

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• Aldrich

• (361887)  (1S,2S)-(+)-Thiomicamine  99%

• 16854-32-3

• 361887-25G

• 1,232.01CNY

• Detail

16854-32-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	(1S,2S)-(+)-2-AMINO-1-[4-(METHYLTHIO)PHENYL]-1,3-PROPANEDIOL

1.2 Other means of identification

Product number	-
Other names	[S(R*,R*)]-2-amino-1-[p-(methylthio)phenyl]propane-1,3-diol

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16854-32-3 SDS

16854-32-3Upstream product

• 95448-24-1 (1S,2S)-threo-2-benzamido-1-(4-methylthiophenyl)-1,3-propanediol 
• 122934-50-3 (S)-(4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 122934-50-3 (S)-(4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 122934-51-4 (4-Methylsulfanyl-phenyl)-(2-phenyl-4,5-dihydro-oxazol-4-yl)-methanone 
• 38423-42-6 N-[1-hydroxymethyl-2-(4-methylsulfanyl-phenyl)-2-oxo-ethyl]-acetamide 
• 23150-33-6 (1RS,2RS)-2-acetylamino-1-(4-methylsulfanyl-phenyl)-propane-1,3-diol 
• 135266-97-6 (2RS,3SR)-2-amino-3-hydroxy-3-(4-methylsulfanyl-phenyl)-propionic acid ethyl ester 
• 119293-92-4 (+/-)-2-dichloroacetamido-β-hydroxy-4-methylmercaptopropiophenone 
• 14052-59-6 D-threo-1-p-methylmercaptophenyl-2-dichloroacetamidopropane-1,3-diol 
• 14172-52-2 (1RS,2RS)-2-amino-1-(4-methylsulfanyl-phenyl)-propane-1,3-diol 

16854-32-3Downstream Products

• 4302-89-0 (1RS,2RS)-2-(2,2-dichloro-acetylamino)-1-(4-methylsulfanyl-phenyl)-propane-1,3-diol 
• 23150-35-8 (R*,R*)-(+)-thiomicamine 
• 71830-03-0 (1S,2S)-2-(2,2-dichloro-acetylamino)-1-(4-methylsulfanyl-phenyl)-propane-1,3-diol 
• 122934-50-3 (R)-(4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 14172-52-2 2-Amino-1-(4-methylsulfanyl-phenyl)-propane-1,3-diol 
• 122934-51-4 (4-Methylsulfanyl-phenyl)-(2-phenyl-4,5-dihydro-oxazol-4-yl)-methanone 
• 122934-51-4 (4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanone 
• 122934-50-3 (S)-(4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 122934-50-3 (S)-(4-Methylsulfanyl-phenyl)-((S)-2-phenyl-4,5-dihydro-oxazol-4-yl)-methanol 
• 906548-44-5 (1S,2S)-(+)-2-(dimethylamino)-1-[4-(methylthio)phenyl]propane-1,3-diol 
• 203576-39-0 (4S,5S)-4-hydroxymethyl-2-methyl-5-[4-(methylthio)phenyl]-2-oxazoline 
• 696659-62-8 (1S,2S)-2-o-toluamide-1-[4-(methylthio)phenyl]-1,3-propanediol 

16854-32-3Relevant articles and documents

NEW STRATEGY FOR RACEMIZATION OF 2-AMINO-1,3-PROPANEDIOLS, KEY INTERMEDIATES FOR THE SYNTHESIS OF ANTIBIOTIC DRUGS

Giordano, Claudio,Cavicchioli, Silvia,Levi, Silvio,Villa, Marco

, p. 5561 - 5564 (2007/10/02)

A new strategy for racemization of the 2-amino-1,3-propanediol 2b, based on a chemoselective oxazoline ring formation and a highly diastereoselective reduction of the ketone 4 is reported.

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