1988-88-1Relevant articles and documents
Rearrangement fragmentation of aldoxime to isocyanide
Nikiforov,Chervin,Ershov,Kostyanovsky
, p. 2029 - 2029 (1996)
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Crystal Engineering and Substituent Effect of Hindered Phenols for SHG Materials
Takagi, Koichi,Mizuno, Akira,Kubata, Michiru,Mizoguchi, Akira,Furushow, Masaru,Matsuoka, Masaru
, p. 1743 - 1746 (2007/10/02)
2,6-di-tert-butylphenol moiety was found to be effective to control molecular packing in crystals for SHG materials.Many derivatives having compact acceptor group at 4-position of hindered phenols showed SHG responses depending on the electron withdrawing effect of an acceptor.The X-ray structural analyses revealed that molecular packing was controlled both by the steric requirements and the intermolecular hydrogen bonding.
OXIDATION OF 2,6-DI-tert-BUTYL-4-METHYLPHENOL BY OXYGEN IN AQUEOUS AMMONIA SOLUTION
Fedulina, T. G.,Deineko, I. P.,Zenkevich, I. G.,Zarubin, M. Ya.
, p. 1373 - 1377 (2007/10/02)
Both monomeric and dimeric oxidation products are formed during the oxidation of 2,6-di-tert-butyl-4-methylphenol (ionole) by oxygen in a water-propanol solution of ammonia.Two nitrogen-containing compounds 3,3'-5,5'-tetra-tert-butylindophenol and 2,6-di-tert-butyl-4-cyanophenol are also formed, and their amounts in the reaction mixture increase with increase in temperature (45-120 deg C).