19894-78-1Relevant articles and documents
Preparation of the geranyl-α-pyrone (±)-aurantiacone via a new pyrone synthesis
Schmidt, Dietmar,Conrad, Jürgen,Klaiber, Iris,Mika, Sabine,Beifuss, Uwe
, p. 333 - 335 (2007)
The structure of the leaf resin geranyl-α-pyrone auranti-acone isolated from Mimulus (= Diplacus) aurantiacus (Curtis) Jeps. (Scrophulariaceae) was confirmed through synthesis. The key step is lactonization of the sensitive 5-hydroxy-3-oxopent-4-enoic acid under mild conditions, which can be released from the corresponding bispotassium salt. The latter is accessible in a few steps from an N-acyl aziridine and an ethyl acetoacetate. Georg Thieme Verlag Stuttgart.
A total synthesis of grifolin
Ohta,Nozaki,Ohashi,Matsukawa,Okamoto
, p. 2239 - 2243 (2007/10/02)
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