1000163-40-5Relevant academic research and scientific papers
Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Ochiai, Hidenori,Uetake, Yuta,Niwa, Takashi,Hosoya, Takamitsu
supporting information, p. 2482 - 2486 (2017/02/23)
Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
Highly versatile enantioselective conjugate addition of grignard reagents to α,β-unsaturated thioesters
Ruiz, Beatriz Macia,Geurts, Koen,Fernandez-Ibanez, M. Angeles,Horst, Bjoern Ter,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 5123 - 5126 (2008/03/28)
Herein, we report efficient catalysts for the asymmetric copper-catalyzed conjugate addition of Grignard reagents to α,β-unsaturated thioesters. MeMgBr adds to aromatic α,β-unsaturated thioesters with excellent enantioselectivities and moderate to good yi
