100033-92-9

Basic information

• Product Name: 3-Bromo-2-methoxy-5-trifluoromethylpyridine
• Synonyms: Bromides;((4-Bromo-3-methylphenyl)carbonyl)morpholine;(4-Bromo-3-methylphenyl)(morpholino)methanone;(3-Bromobenzoyl)pyrrolidine;(3-Bromophenyl)(pyrrolidin-1-yl)methanone;(4-Bromo-2-fluorophenyl)(4-methoxybenzyl)sulfane;S-(4-Methoxybenzyl) 4-bromo-2-fluorothiophenol;(4-Bromo-3-methylphenyl)(pyrrolidin-1-yl)methanone
• CAS NO: 100033-92-9
• Molecular Weight: 240.207
• Mol File: 100033-92-9.mol
• Article Data: 4

Chemical Properties

• Melting Point: 45-46°C
• CAS DataBase Reference: 3-Bromo-2-methoxy-5-trifluoromethylpyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromo-2-methoxy-5-trifluoromethylpyridine(100033-92-9)
• EPA Substance Registry System: 3-Bromo-2-methoxy-5-trifluoromethylpyridine(100033-92-9)

Safety Data

• Hazardous Substances Data: 100033-92-9(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 
• 109-73-9 N-butylamine 
• 5977-82-2 selenobenzamide 
• 98-87-3 benzylidene dichloride 

Relevant articles and documents

A Willgerodt-Kindler Type Selenation of Dihalomethane Derivatives, Chloroform, and Sodium Trichloroacetate by Treating with a Base, Elemental Selenium, and an Amine

Treatment of dihalomethane derivatives, chloroform, or sodium trichloroacetate with elemental selenium in the presence of NaH and an excess amount of an amine gave the corresponding selenoamides, selenoureas, and bis(selenocarbamoyl) triselenides in modest yields. These products were afforded from reactive intermediates related to "selenocarbonyl halides" and "selenophosgenoids" generated by the reaction of dichloromethanide ions and trichloromethanide ion with N-alkylated aminopolyselenide species (R2N-(Se)n-).

Convenient Syntheses of N,N-Dialkylselenoamides and N,N,N',N'-Tetraalkylselenoureas by Treating Terminal gem-Dihaloalkanes, Chloroform , or Sodium Trichloroacetate with a Base, Elemental Selenium, and Amines

Treatment of terminal gem-dihaloalkanes, chloroform or sodium trichloroacetate with elemental selenium in the presence of NaH and an excess amount of primary or secondary amines gave selenoamides and selenoureas in modest yields.