100043-01-4Relevant articles and documents
Preparation and photoactivity of a novel water-soluble, polymerizable zinc phthalocyanine
Shen, Xiaoyuan,Lu, Wangyang,Feng, Guihua,Yao, Yuyuan,Chen, Wenxing
, p. 17 - 22 (2009)
A novel water-soluble and polymerizable photosensitizer, zinc tetra(N-carbonylacrylic)aminophthalocyanine (Zn-MPc), was synthesized by the ornament of zinc tetraaminophthalocyanine (Zn-APc) with maleic anhydride and characterized by 1H NMR, FT-
Graphene oxide–metallophthalocyanine hybrids with enhanced singlet oxygen generation
Rocha, Fellipy S.,Gomes, Anderson J.,Lunardi, Claure N.
, p. 45 - 51 (2019)
Graphene oxide (GO) was added to zinc phthalocyanine (ZnPc) and tetra nitro substituted zinc phthalocyanine (ZnPc(NO2)4) solutions to evaluate the photophysical interaction of GO with ph- thalocyanines. Dimethylformamide (DMF) and acetonitrile (MeCN) were used as solvents. GO quenching is shown to be stronger with ZnPc(NO2)4, presenting a Stern-Volmer (Ksv) constant ap- proximately 10 times higher than ZnPc. The presence of GO and the increase in its concentration demonstrates a different pattern of absorbance for ZnPc(NO2)4. Singlet oxygen generation was found to be higher in DMF than MeCN enhaces with GO present. The overall singlet quantum yield of ZnPc is higher than ZnPc(NO2)4.
Synthesis and spectral studies on substituted metal (II)-tetra-1-(thiophene-2-yl)methanimine phthalocyanine complexes
Fasiulla,Yashoda
, p. 1526 - 1532 (2018)
The synthesis, characterization of symmetrically substituted transition metal (ΙΙ)–tetra-1-(thiophene-2-yl) methaniminephthalocyanine complexes by condensation of tetraamino phthalocyanines with 2-thiophenecarboxaldehyde had been prepared. The structural and characterization of theblue colour tetra -1-(thiophene-2- yl)methanimine phthalocyanine complexesare elucidated by using a number of analytical techniques like FT-Infrared, UV-Vis spectroscopy, XRD, magnetic measurements and thermo-gravimetric analysis.The kinetic parameters and thermal decomposition of synthesized phthalocyanines complexes were calculated using thermo-gravimetric analytical data.
Synthesis of new zinc(II) phthalocyanine conjugates with block copolymers for cancer therapy
Lamch, Lukasz,Tsirigotis-Maniecka, Marta,Kulbacka, Julita,Wilk, Kazimiera A.
, p. 433 - 445 (2017/03/09)
Synthetic routes towards new conjugates of hydrophilic zinc(II) phthalocyanine (ZnPc) with poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (Pluronic P123) and poly(L-lactide) (PLLA), are described. The main semiproduct ZnPc was obtained by heating 4-nitrophthalimide with urea and zinc chloride, followed by the reduction step. Steglich esterification was used to synthesize two ZnPc-conjugated block copolymers, further utilized in fabrication of polymeric micelles (PMs)-functionalized with the zinc(II) phthalocyanine-type moiety. Biological evaluation of the PMs indicated an acceptable biocompatibility level in accord with requirements in the field of nanotheranostics and nanomedicine.