1000591-73-0Relevant articles and documents
An Inhospitable Cryptand: The Importance of Conformational Freedom in Host-Guest Complexation
Gibson, Harry W.,Huang, Feihe,Zhao, Run,Shao, Li,Zakharov, Lev N.,Slebodnick, Carla,Rheingold, Arnold L.
, p. 3472 - 3479 (2019)
Two new cryptands were synthesized from bis(5-bromomethyl-1,3-phenylene)-32-crown-10 (4). The third arms, containing 19 or 21 atoms, were installed via Williamson ether syntheses with bisphenols containing 2,6-disubstituted pyridines. 2,6-Diaminopyridine
A switchable palladium-complexed molecular shuttle and its metastable positional isomers
Crowley, James D.,Leigh, David A.,Lusby, Paul J.,McBurney, Roy T.,Perret-Aebi, Laure-Emmanuelle,Petzold, Christiane,Slawin, Alexandra M. Z.,Symes, Mark D.
, p. 15085 - 15090 (2008/09/17)
We report the design, synthesis, characterization, and operation of a [2]rotaxane in which a palladium-complexed macrocycle can be translocated between 4-dimethylaminopyridine and pyridine monodentate ligand sites via reversible protonation, the metal rem