100060-27-3Relevant articles and documents
THE STUDIES OF METAL ION CATALYZED CARBON-HYDROGEN INSERTION OF α-ALKOXY-α'-DIAZOKETONES DERIVED FROM MANDELIC AND LACTIC ACIDS
Hon, Yung-Son,Chang, Rong-Chi,Chau, Tay-Yuan
, p. 1745 - 1750 (2007/10/02)
The cupric acetylacetonate is the best catalyst to induce the carbon-hydrogen inserted reaction for the α-alkoxy-α'-diazoketones derivatives (5 and 6).The side reactions such as aromatic carbon-hydrogen insertion and rearrangement could be prevented.
Rhodium Acetate Catalyzes the Addition of Carbenoids α- to Ether Oxygens
Adams, Julian,Poupart, Marc-Andre,Grenier, Louis,Schaller, Chris,Ouimet, Nathalie,Frenette, Richard
, p. 1749 - 1752 (2007/10/02)
Diazo-carbonyl compounds, when catalyzed by rhodium acetate, insert preferentially adjacent to ether oxygens.This phenomenon was exploited to develop a synthesis of 3(2H)-furanones.