1000992-61-9

Upstream product

• 1000992-53-9 C₁₅H₁₈O 
• 1001386-09-9 (2-bromocyclohex-1-en-1-yl)(phenyl)methanone 
• 925-90-6 ethylmagnesium bromide 
• 1228319-68-3 α-(2-bromocyclohexen-1-yl)benzyl alcohol 
• 38127-47-8 2-bromocyclohex-1-ene-1-carbaldehyde 
• 108-94-1 cyclohexanone 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 1279102-88-3 C₂₄H₂₄O₂ 
• 1279102-67-8 ((Z)-(E)-2-(ethylidene)cyclohexylidene(phenyl)methoxy)trimethylsilane 

Relevant academic research and scientific papers

Enabling the development of N-Heterocyclic Carbene (NHC) catalyzed reactions: Practical methods for the preparation of 1-acyl-2-alkylcycloalkenes from cycloalkanones

The synthesis of 1-acyl-2-alkylcycloalkenes from a variety of cycloalkanones has been achieved via either-keto enol phosphates or-bromoenones. Both methods exploit simple and readily scalable transformations allowing the preparation of the desired compoun

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.

Gold-catalyzed intramolecular carbocyclization of alkynyl ketones leading to highly substituted cyclic enones

(Chemical Equation Presented) The reaction of the internal alkynyl ketones 1 (n = 1) under the combined catalyst, AuCl3 and AgSbF6, gave the enones 2 in good to high yields, whereas that of the terminal alkynyl ketones 1 (n = 0) unde