1228319-68-3

Upstream product

• 38127-47-8 2-bromocyclohex-1-ene-1-carbaldehyde 
• 100-58-3 phenylmagnesium bromide 
• 108-94-1 cyclohexanone 

Downstream Products

• 1001386-09-9 (2-bromocyclohex-1-en-1-yl)(phenyl)methanone 
• 1333961-19-5 phenyl(2-propylcyclohex-1-en-1-yl)methanone 
• 1333961-20-8 C₁₆H₁₉BrO 
• 1447908-78-2 4-(3-phenyl-4,5,6,7-tetrahydro-2-benzofuran-1-yl)-1-butanol 
• 1447908-94-2 (2R,3R,4R)-1,3,4-trimethoxy-5-(3-phenyl-4,5,6,7-tetrahydro-2-benzofuran-1-yl)-2-pentanol 
• 32704-49-7 (2-methylcyclohex-1-en-1-yl)(phenyl)methanone 
• 1279102-84-9 2-(4-phenyl-1,2,5,6,7,8-hexahydronaphthalen-2-yl)furan 
• 1279102-83-8 6-(2-bromocyclohex-1-en-1-yl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-82-7 6-(4-methoxyphenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-81-6 6-(3-bromophenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-80-5 6-(2-methoxyphenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-79-2 6-(2-nitrophenyl)-8-phenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-70-3 6,8-diphenyl-1,2,3,4,5,6-hexahydronaphthalene 
• 1279102-71-4 (Z)-(2-methylenecyclohexylidene)(phenyl)methyl cinnamate 

Relevant academic research and scientific papers

Palladium-catalyzed carbonylative cyclization of 3-bromoallyl alcohols leading to furan-2(5H)-ones

3-Bromoallyl alcohols are carbonylatively cyclized under carbon monoxide pressure in toluene in the presence of a catalytic amount of Pd(OAc)2 and PPh3 along with Na2CO3 to give furan-2(5H)-ones in good yields.

N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides

Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting α,β-unsaturated acyl azoliums.

Enabling the development of N-Heterocyclic Carbene (NHC) catalyzed reactions: Practical methods for the preparation of 1-acyl-2-alkylcycloalkenes from cycloalkanones

The synthesis of 1-acyl-2-alkylcycloalkenes from a variety of cycloalkanones has been achieved via either-keto enol phosphates or-bromoenones. Both methods exploit simple and readily scalable transformations allowing the preparation of the desired compoun

Atom-efficient synthesis of α-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds

The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl2 afforded the α-alkylidene-N-furylimines with high stereoselectivities.