100102-47-4

Upstream product

• 78391-93-2 Methyl-2-O-benzoyl-6-desoxy-α-D-glucopyranosid 
• 5155-43-1 methyl 6-deoxy-α-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 100164-72-5 Methyl-3,4,6-tridesoxy-α-D-erythro-hex-3-enopyranosid 
• 63902-64-7 Methyl-3,4,6-tridesoxy-β-D-erythro-hex-3-enopyranosid 
• 61135-30-6 Methyl-3,4,6-tridesoxy-β-D-glycero-hex-3-enopyranosid-2-ulose 
• 100164-74-7 Methyl-3,4,6-tridesoxy-β-D-threo-hex-3-enopyranosid 
• 65-85-0 benzoic acid 

Downstream Products

• 78294-36-7 Methyl-2-O-acetyl-4,6-didesoxy-4-(4-methylphenylsulfonylamino)-α-D-altropyranosid 
• 78294-37-8 Methyl-2-O-acetyl-3,6-didesoxy-3-(4-methylphenylsulfonylamino)-α-D-altropyranosid 

Relevant academic research and scientific papers

Syntheses of Biologically Important Carbohydrates, 33. - Syntheses of Unsaturated Amino Sugars and Aminoalkyl-branched Carbohydrates via Sigmatropic Rearrangement of Trichloroacetimidates

Starting with the α-D-erythro-hex-3-enopyranoside 1 the isomers with β-D-erythro as well as α- and β-D-threo configuration 5b, 3b, and 9 are prepared.In Mitsunobu reactions the 1,2-cis derivatives 1 and 9 smoothly undergo SN2-type substitutions

Syntheses of Biologically Important Carbohydrates, 25. On the Regioselectivity of the Sharpless Reaction; The vic. cis-Oxyamination of Unbranched and 3-C-Branched Ald-2- and Ald-3-enopyranosides

The configurations and the ratios of regioisomeric amino sugars obtained by vic. cis-oxyamination of unsaturated carbohydrates 1, 4, 9, 16, 19, 21 are determined.Due to the ratios of amino sugars from the ald-3-enopyranosides 9 and 16 it is obvious that t