100228-74-8

Basic information

• Product Name: Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*C₅H₅^(1-)*C₄H₈O=(Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)C₅H₅*C₄H₈O
• CAS NO: 100228-74-8
• Molecular Weight: 1126.27
• Mol File: 100228-74-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*C₅H₅^(1-)*C₄H₈O=(Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)C₅H₅*C₄H₈O(CAS DataBase Reference)
• NIST Chemistry Reference: Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*C₅H₅^(1-)*C₄H₈O=(Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)C₅H₅*C₄H₈O(100228-74-8)
• EPA Substance Registry System: Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*C₅H₅^(1-)*C₄H₈O=(Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)C₅H₅*C₄H₈O(100228-74-8)

Safety Data

• Hazardous Substances Data: 100228-74-8(Hazardous Substances Data)

Upstream product

• 15390-38-2 Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*Cl^(1-)=Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2Cl 
• 16733-97-4 cyclopentadienyllithium 

Downstream Products

• 79292-53-8 IrHCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)=(IrHCl((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)BF₄ 

Relevant articles and documents

Some chemistry of alkyl complexes of bis(1,2-bis(diphenylphosphino)ethane)iridium(I)

New five-coordinate Ir(I) alkyl complexes have been prepared by the addition of LiR (R = CH3, C5H5) to [Ir(dppe)2]Cl (dppe = 1,2-bis(diphenylphosphino)ethane). IrMe(dppe)2 is found to be very reactive toward acid, forming cis-IrH(Me)(dppe)2+, and toward CO and CO2. In contrast, the cyclopentadienyl complex [Ir(dppe)2]Cp is ionic and shows the reactivity of the Ir(dppe)2+ cation. That this complex is ionic is apparently not a result of steric constraints. A X-ray structural study of IrMe(dppe)2 indicates that the coordination geometry about the Ir center is that of a distorted trigonal bipyramid with the Me group in an axial position; Ir-Me = 2.189 (8) ?.