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Upstream product

• 15390-38-2 Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*Cl^(1-)=Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2Cl 
• 91606-11-0 IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2 
• 91685-25-5 IrCl(CO)(((C₆H₅)2PCH₂)2)2⁽²⁺⁾*2BF₄^(1-) = [IrCl(CO)(((C₆H₅)2PCH₂)2)2](BF₄)2 
• 67969-82-8 tetrafluoroboric acid diethyl ether 
• 100228-74-8 Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2⁽¹⁺⁾*C₅H₅^(1-)*C₄H₈O=(Ir((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2)C₅H₅*C₄H₈O 

Relevant academic research and scientific papers

Some chemistry of alkyl complexes of bis(1,2-bis(diphenylphosphino)ethane)iridium(I)

New five-coordinate Ir(I) alkyl complexes have been prepared by the addition of LiR (R = CH3, C5H5) to [Ir(dppe)2]Cl (dppe = 1,2-bis(diphenylphosphino)ethane). IrMe(dppe)2 is found to be very reactive toward acid, forming cis-IrH(Me)(dppe)2+, and toward CO and CO2. In contrast, the cyclopentadienyl complex [Ir(dppe)2]Cp is ionic and shows the reactivity of the Ir(dppe)2+ cation. That this complex is ionic is apparently not a result of steric constraints. A X-ray structural study of IrMe(dppe)2 indicates that the coordination geometry about the Ir center is that of a distorted trigonal bipyramid with the Me group in an axial position; Ir-Me = 2.189 (8) ?.

Carbon monoxide activation by iridium(III) dicationic carbonyl complexes

The cationic cis- and trans-IrX(CO)(dppe)22+ (X = H, Cl) species react with nucleophiles, such as H2O, OH-, and H-, to afford hydroxycarbonyl and formyl cations of Ir(III) typified by the species tran