10035-01-5

Usage

Uses

Used in Fluorescent Materials Industry:
Ytterbium(III) chloride hexahydrate is used as a rare earth dopant for the development of yttrium oxide (Y2O3) nanoparticles. This application is crucial in the creation of fluorescent materials, which have various uses in different fields, including medical imaging, lighting, and display technologies.
Used in 3D Displays and Photovoltaics Industry:
Ytterbium(III) chloride hexahydrate is also used as a dopant for yttrium fluoride (YF3) nanoparticles, which have potential applications in 3D displays, photovoltaics, and drug delivery systems. The doping process enhances the optical and electronic properties of the nanoparticles, making them suitable for these advanced technologies.
Used in Drug Delivery Systems:
In the pharmaceutical industry, ytterbium(III) chloride hexahydrate can be utilized in the development of drug delivery systems. The unique properties of ytterbium-based nanoparticles can be harnessed to improve the targeting, release, and overall efficacy of drug delivery, potentially leading to more effective treatments for various medical conditions.

InChI:InChI=1/3ClH.6H2O.Yb/h3*1H;6*1H2;/q;;;;;;;;;+2/p-3

Upstream product

• 7647-01-0 hydrogenchloride 
• 7732-18-5 water 

Downstream Products

• 114363-84-7 YbCl₃*H₂O 
• 113128-27-1 [5,10,15,20-tetraphenylporphinato]ytterbium(III) chloride 
• 1261477-35-3 ((HSC₆H₄NHCOCH₂NCH₂COOC₂H₄)2NCH₂COO)Yb 

Relevant academic research and scientific papers

The mononuclear and dinuclear dimethoxyethane adducts of lanthanide trichlorides [LnCl3(DME)2]n, n=1 or 2, fundamental starting materials in lanthanide chemistry: Preparation and structures

Some new dimethoxyethane (DME) adducts of lanthanide trichlorides of formula [LnCl3(DME)2]n, n=1 or 2; (n=2, Ln=La, Ce, Pr, Nd; n=1, Ln=Eu, Tb, Ho, Tm, Lu) have been prepared by treating Ln 2O3, or LnCl3·nH2O, or Ln2(CO3)3, in DME as medium, with thionyl chloride at room temperature, eventually in the presence of water in the case of Ln2O3 and Ln2(CO3)3. The complexes from lanthanum to praseodymium included are chloro-bridged dimers. In the case of neodymium, the new results complement the literature data, showing that both the mononuclear and dinuclear species exist: neodymium can therefore be regarded as the turning element from dinuclear to mononuclear structures along the series. Only mononuclear complexes were isolated in the Eu-Lu sequence. The lanthanide contraction has been evaluated on the basis of the Ln-O and Ln-Cl bond distances on the isotypical series of the mononuclear complexes LnCl3(DME)2 covering a range of 12 atomic numbers.

Near-infrared luminescence from visible-light-sensitized hybrid materials covalently linked with tris(8-hydroxyquinolinate)-lanthanide [Er(III), Nd(III), and Yb(III)] derivatives

A series of new near-infrared (NIR) luminescent lanthanide-quinolinate derivatives [Ln(Q-Si)3] and xerogels (named as LnQSi-Gel, Ln = Er, Nd, Yb) covalently linked with the Ln(Q-Si)3 by using the 8-hydroxyquinoline-functionalized alkoxysilane (Q-Si) have been synthesized. The obtained xerogel materials LnQSi-Gel are rigid and show homogeneous by field-emission scanning electron microscopy (FE-SEM) images. The Fourier-transform infrared (FT-IR), fluorescence spectra of Ln(Q-Si) 3, and LnQSi-Gel were measured, and the corresponding luminescence decay analyses were recorded. Of importance here is that the excitation spectra of the Ln(Q-Si)3 and LnQSi-Gel extend to the region of visible light (more than 500 nm). Upon ligand-mediated excitation with the visible light, the Ln(Q-Si)3 and LnQSi-Gel show the characteristic NIR-luminescence of the corresponding lanthanide ions through the intramolecular energy transfer from the ligands to the lanthanide ions. The good luminescent performances enable these NIR-luminescent xerogel materials to have possible applications in medical diagnostics, laser systems, and optics, etc.

Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4′-oxybis(benzoic acid)

Three new polynuclear lanthanide coordination polymers [Ln 5(μ3-OH)(oba)7(H2O) 2]n ? 0.5nH2O (Ln = Eu (1), Ho (2)) and [Yb6(oba)9(H2O)]n (3) (H 2oba = 4,4′-oxybis(benzoic acid)), were prepared by hydrothermal reactions. 1 and 2 are isomorphous and exhibit complicated three-dimensional structures based on [Ln5(μ 3-OH)(oba)7(H2O)2] building blocks. In the asymmetric unit, there are five different coordination environments of Ln(III) ions, including a trinuclear hydroxo core. Complex 3 is a three-dimensional coordination polymer built up from a hexanuclear building block. In 3, Yb(III) ions have six different chemical environments and are in a regular arrangement, resulting in pseudohexagonal prisms along the a-axis. The luminescent property of 1 and magnetic behaviors of 2 and 3 have also been studied.

Synthesis process and the luminescence properties of rare earth doped NaLa(WO4)2 nanoparticles

Rare earth doped NaLa(WO4)2 nanoparticles have been prepared by a simply hydrothermal synthesis procedure. The X-ray diffraction (XRD) pattern shows that the Eu3+-doped NaLa(WO4)2 nanoparticles with an average size of 10-30 nm can be obtained via hydrothermal treatment for different time at 180 °C. The luminescence intensity of Eu3+-doped NaLa(WO4)2 nanoparticles depended on the size of the nanoparticles. The bright upconversion luminescence of the 2 mol% Er3+ and 20 mol% Yb3+ codoped NaLa(WO4)2 nanoparticles under 980 nm excitation could also be observed. The Yb3+-Er3+ codoped NaLa(WO4)2 nanoparticles prepared by the hydrothermal treatment at 180 °C and then heated at 600 °C shows a 20 times stronger upconversion luminescence than those prepared by hydrothermal treatment at 180 °C or by hydrothermal treatment at 180 °C and then heated at 400 °C.

Investigation of desolvation process in lanthanide dinicotinates

The desolvation process in lanthanide pyridine-3,5-dicarboxylates of the formulae [Tb2pdc3(dmf)2]?dmf (1), [Ho 2pdc3(dmf)2]?dmf (2), [Erdc 3(dmf)2]?dmf (3), and [Yb2pdc 3(dmf)2]?dmf (4) where pdc-C5H 3N(COO) 2 2-, dmf-N,N′-dimethylformamide) has been investigated by means of the TG-DSC, TG-FTIR, IR and XRD methods. Heating of the complexes in the range 30-260 °C lead to evolution of weakly bonded dmf molecules included in the channels as well those directly bonded with lanthanide atoms. The kinetic analysis revealed a multistep desolvation pattern.

Synthesis, structure, thermal and luminescent behaviors of lanthanide-Pyridine-3,5-dicarboxylate frameworks series

The isostructural series of lanthanide pyridine-3,5-dicarboxylates of the formula [Ln2pdc3(dmf)2]·(dmf) x(H2O)y where Ln are lanthanides from La(III) to Lu(III); pdc2--C5/s

Thermochemical properties of the rare earth complexes with pyromellitic acid

Fourteen rare earth complexes with pyromellitic acid were synthesized and characterized by means of chemical and elemental analysis, and TG-DTG. The constant-volume combustion energies of complexes, ΔcU, were measured by a precise rotating-bomb

Synthesis, structure, and antibacterial properties of ternary rare-earth complexes with o-methylbenzoic Acid and 1,10-phenanthroline1

Ternary rare-earth complexes with o-methylbenzoic acid (o-MBA) and 1,10-phenanthroline (Phen) Ln2(o-MBA)6(Phen)2 ? nH2O(n = 0, 1) (Ln = La, Pr, Y, Yb) were synthesized and characterized by elemental analysis, IR

Solubility in the LaCl3-YbCl3-HCl-H2O system at 25°C

Solubility has been studied in the LaCl3-YbCl 3-HCl-H2O water-salt system at 25°C along the (40 ± 0.2)% HCl section; this is a eutonic-type system. The composition of the eutonic solution is as follows (wt %): LaCl3 ? 7H 2O, 4.67, YbCl3 ? 6H2O, 0.37; HCl, 37.98; and H2O, 56.98.

Lanthanide complexes with 16- and 18-membered dibenzo-substituted macroheterocyclic ligands

The luminescence characteristics of Eu(III) and Yb(III) complexes with 16- and 18-membered dibenzo-substituted macroheterocyclic ligands were determined and their relationship with the complex composition was examined. It was shown that the low 4f luminescence intensity is caused by the inefficient excitation energy transfer from the triplet levels of the ligands to the resonance levels of the lanthanide ions. Copyright