10035-01-5

Basic information

• Product Name: YTTERBIUM(III) CHLORIDE HEXAHYDRATE
• Synonyms: YtterbiuM(III) chloride hexahydrate 99.9% trace Metals basis;YtterbiuM(III) chloride hexahydrate 99.998% trace Metals basis;Ytterbium chloride(YbCl3), hexahydrate (7CI,8CI,9CI);Ytterbium trichloride hydrate;Ytterbium trichloride hydrate ,Ytterbium(III) chloride·6hydrate;YTTERBIUM(+3)CHLORIDE HEXAHYDRATE;YTTERBIUM(III) CHLORIDE HEXAHYDRATE;YTTERBIUM (III) CHLORIDE
• CAS NO: 10035-01-5
• Molecular Formula: Cl3H12O6Yb
• Molecular Weight: 387.49
• EINECS: 237-632-3
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Salts;Ytterbium Salts;YtterbiumMetal and Ceramic Science
• Mol File: 10035-01-5.mol
• Article Data: 21

Chemical Properties

• Melting Point: 180 °C (dec.)(lit.)
• Appearance: White/Powder
• Density: 2.58 g/mL at 25 °C(lit.)
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: very soluble H2O [HAW93]
• Stability: Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: YTTERBIUM(III) CHLORIDE HEXAHYDRATE(CAS DataBase Reference)
• NIST Chemistry Reference: YTTERBIUM(III) CHLORIDE HEXAHYDRATE(10035-01-5)
• EPA Substance Registry System: YTTERBIUM(III) CHLORIDE HEXAHYDRATE(10035-01-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 10035-01-5(Hazardous Substances Data)

Usage

Description

Ytterbium (III) chloride hexahydrate is a stable, hygroscopic (absorbs moisture from the air), moisture-sensitive compound. It is incompatible with strong oxidising agents. Exposure to ytterbium (III) chloride hexahydrate has been reported to cause eye irritation, skin irritation, and respiratory tract irritation.

Chemical Properties

solid

Uses

Ytterbium(III) chloride hexahydrate can be used in applications such as: rare earth doping of yttrium oxide (Y2O3) nanoparticles for the development of fluorescent materials, doping of yttrium fluoride (YF3) nanoparticles for potential usage in 3D displays, photovoltaics, and drug delivery

InChI:InChI=1/3ClH.6H2O.Yb/h3*1H;6*1H2;/q;;;;;;;;;+2/p-3

Upstream product

• 7647-01-0 hydrogenchloride 
• 7732-18-5 water 

Downstream Products

• 114363-84-7 YbCl₃*H₂O 
• 113128-27-1 [5,10,15,20-tetraphenylporphinato]ytterbium(III) chloride 
• 686289-29-2 [Yb(III)Cl₂(triphenylphosphine oxide)4]PF₆ 
• 1261477-35-3 ((HSC₆H₄NHCOCH₂NCH₂COOC₂H₄)2NCH₂COO)Yb 

Relevant articles and documents

The mononuclear and dinuclear dimethoxyethane adducts of lanthanide trichlorides [LnCl3(DME)2]n, n=1 or 2, fundamental starting materials in lanthanide chemistry: Preparation and structures

Some new dimethoxyethane (DME) adducts of lanthanide trichlorides of formula [LnCl3(DME)2]n, n=1 or 2; (n=2, Ln=La, Ce, Pr, Nd; n=1, Ln=Eu, Tb, Ho, Tm, Lu) have been prepared by treating Ln 2O3, or LnCl3·nH2O, or Ln2(CO3)3, in DME as medium, with thionyl chloride at room temperature, eventually in the presence of water in the case of Ln2O3 and Ln2(CO3)3. The complexes from lanthanum to praseodymium included are chloro-bridged dimers. In the case of neodymium, the new results complement the literature data, showing that both the mononuclear and dinuclear species exist: neodymium can therefore be regarded as the turning element from dinuclear to mononuclear structures along the series. Only mononuclear complexes were isolated in the Eu-Lu sequence. The lanthanide contraction has been evaluated on the basis of the Ln-O and Ln-Cl bond distances on the isotypical series of the mononuclear complexes LnCl3(DME)2 covering a range of 12 atomic numbers.

Synthesis and characterization of new polynuclear lanthanide coordination polymers with 4,4′-oxybis(benzoic acid)

Three new polynuclear lanthanide coordination polymers [Ln 5(μ3-OH)(oba)7(H2O) 2]n ? 0.5nH2O (Ln = Eu (1), Ho (2)) and [Yb6(oba)9(H2O)]n (3) (H 2oba = 4,4′-oxybis(benzoic acid)), were prepared by hydrothermal reactions. 1 and 2 are isomorphous and exhibit complicated three-dimensional structures based on [Ln5(μ 3-OH)(oba)7(H2O)2] building blocks. In the asymmetric unit, there are five different coordination environments of Ln(III) ions, including a trinuclear hydroxo core. Complex 3 is a three-dimensional coordination polymer built up from a hexanuclear building block. In 3, Yb(III) ions have six different chemical environments and are in a regular arrangement, resulting in pseudohexagonal prisms along the a-axis. The luminescent property of 1 and magnetic behaviors of 2 and 3 have also been studied.

Investigation of desolvation process in lanthanide dinicotinates

The desolvation process in lanthanide pyridine-3,5-dicarboxylates of the formulae [Tb2pdc3(dmf)2]?dmf (1), [Ho 2pdc3(dmf)2]?dmf (2), [Erdc 3(dmf)2]?dmf (3), and [Yb2pdc 3(dmf)2]?dmf (4) where pdc-C5H 3N(COO) 2 2-, dmf-N,N′-dimethylformamide) has been investigated by means of the TG-DSC, TG-FTIR, IR and XRD methods. Heating of the complexes in the range 30-260 °C lead to evolution of weakly bonded dmf molecules included in the channels as well those directly bonded with lanthanide atoms. The kinetic analysis revealed a multistep desolvation pattern.

Synthesis, structure, and antibacterial properties of ternary rare-earth complexes with o-methylbenzoic Acid and 1,10-phenanthroline1

Ternary rare-earth complexes with o-methylbenzoic acid (o-MBA) and 1,10-phenanthroline (Phen) Ln2(o-MBA)6(Phen)2 ? nH2O(n = 0, 1) (Ln = La, Pr, Y, Yb) were synthesized and characterized by elemental analysis, IR