10035-97-9

Basic information

• Product Name: (2Z)-2-Cyclodecene-1-one
• Synonyms: (2Z)-2-Cyclodecene-1-one;(Z)-1-Cyclodecene-3-one;(Z)-2-Cyclodecen-1-one
• CAS NO: 10035-97-9
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 0
• Mol File: 10035-97-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2Z)-2-Cyclodecene-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-2-Cyclodecene-1-one(10035-97-9)
• EPA Substance Registry System: (2Z)-2-Cyclodecene-1-one(10035-97-9)

Safety Data

• Hazardous Substances Data: 10035-97-9(Hazardous Substances Data)

Usage

General Description

(2Z)-2-Cyclodecene-1-one is a chemical compound belonging to the class of organic compounds known as cycloalkenones. It is a cyclic unsaturated ketone with a molecular formula of C10H16O. (2Z)-2-Cyclodecene-1-one is a colorless liquid at room temperature with a strong and unpleasant odor. It is used as a precursor in the synthesis of other organic compounds, and it is also employed in the manufacturing of perfumes and other fragrance products. Additionally, (2Z)-2-Cyclodecene-1-one has potential applications in the field of organic chemistry and is a valuable intermediate in the production of fine chemicals.

Upstream product

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• 37072-27-8 2-Cyclodecenon-aethylen-acetal 
• 75-77-4 chloro-trimethyl-silane 
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Downstream Products

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Relevant articles and documents

Application of Rh(l)-Catalyzed C - H Bond Activation to the Ring Opening of 2-Cycloalkenones in the Presence of Amines

(matrix presented) Herein described is the application of the Rh(l)-catalyzed C-H bond activation to the ring-opening of 2-cycloalkenones in the presence of cyclohexylamine. This reaction includes the C-C double bond cleavage of 2-cycloalkenones through the conjugate addition of cyclohexylamine followed by the retro-Mannich-type fragmentation. The resulting ring-opened intermediates subsequently underwent either chelation-assisted hydroacylation to afford a ring-opened dicarbonyl compound or β-alkylation via a ring contraction.

Recoverable chiral sulfoxides for asymmetric synthesis: application to stereoselective carbonyl reduction and the asymmetric synthesis of allylic alcohols

The enantiomerically pure cyclic sulfinamide S(S)R-(+)-3 reacts with the sodium enolates of ketones to give the corresponding homochiral sulfoxides.Reduction of the carbonyl group in these products may be achieved using a variety of reducing agents the best of which were DIBAL-H or DIBAL-H/ZnBr2, which give complementary products of high diastereomeric excess.Reduction of the hydroxy sulfoxides with Raney nickel proceeds in low yield and causes partial racemisation of the products.However the combined use of a durected reduction followed by a facile sulfenic acid elimination provides a synthesis of allylic alcohols in high enentiomeric excess.