100398-52-5Relevant articles and documents
Copper-Mediated Decarboxylative Sulfonylation of Arylacetic Acids with Sodium Sulfinates
Wu, Yinrong,Chen, Jiewen,Li, Lu,Wen, Kangmei,Yao, Xingang,Pang, Jianxin,Wu, Ting,Tang, Xiaodong
supporting information, p. 7164 - 7168 (2020/10/02)
Herein, we present a copper-mediated decarboxylative sulfonylation of arylacetic acids with sodium sulfinates that provides viable access to sulfone compounds. This protocol features readily available feedstocks, simple operations, high regioselectivities, and moderate to good yields. The newly obtained products could be converted to other useful compounds. Importantly, the products and their derivatives exhibited potent antitumor activities in vitro, which were tested by MTT assay.
3-Carboxypyridinium chlorochromate - aluminium chloride - An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation
Mohammadpoor-Baltork, Iraj,Memarian, Hamid R.,Bahrami, Kiumars
, p. 115 - 121 (2007/10/03)
3-Carboxypyridinium chlorochromate (CPCC) in the presence of aluminium chloride is a very efficient reagent for the selective oxidation of sulfides to sulfoxide and sulfones in solution and under microwave irradiation. It is noteworthy that different functional groups including carbon-carbon double bonds, ketones, oximes, aldehydes, ethers, and acetals were tolerated under these reaction conditions.
PREPARATION AND ALKYLATION REACTIONS OF 4-NITROBENZYL AND 5-NITROFURFURYL SULFONES
Prousek, Josef
, p. 851 - 856 (2007/10/02)
Substitution reaction of 5-nitrofurfuryl bromide (I) with sodium thiophenoxide and 4-chlorothiophenoxide in dimethyl sulfoxide at 20 deg C and oxidation with dimethyl sulfoxide in the reaction medium afforded 5-nitrofurfuryl phenyl sulfone (IVa) and 5-nit