100401-24-9Relevant academic research and scientific papers
Novel catalysis in the internal nanocavity of polyamine dendrimer for intramolecular michael reaction
Maeno, Zen,Mitsudome, Takato,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
, p. 801 - 803 (2012)
Poly(propyleneimine) (PPI) dendrimers functionalized with C16 alkyl chains acted as efficient tertiary amine catalysts for an intramolecular Michael reaction. The substrate was accommodated in a reactive conformation within a sterically confined nanocavity consisting of regularly arranged tertiary amino groups of the PPI dendrimers.
One-pot diastereoselective synthesis of 2-acyl-4-nitrocyclohexanol derivatives in aqueous medium
Ballini, Roberto,Barboni, Luciano,Bosica, Giovanna,Filippone, Paolino,Peretti, Sabina
, p. 4095 - 4099 (2007/10/03)
The reaction of primary nitroalkanes with conjugated enones, in water and in the presence of K2CO3 as base, allows the synthesis of 2-acyl-4- nitrocyclohexanol derivatives in which the diastereoisomer (±)- (1S*,2R*,5R) is highly pred
