1004314-74-2Relevant academic research and scientific papers
Unprecedented formation of μ-vinylidene complexes from phospharuthenocene and acyl chloride via activation of the C=O double bond
Ogasawara, Masamichi,Sakamoto, Takeshi,Ito, Azumi,Ge, Yonghui,Nakajima, Kiyohiko,Takahashi, Tamotsu,Hayashi, Tamio
, p. 6698 - 6700 (2008/10/09)
A novel reaction mode of phosphametallocenes was discovered. The phospharuthenocenes with cyclohexyl substituents at the α-positions of the η5-phospholide(s) reacted with acyl electrophiles by an initial electrophilic attack to the ruthenium to produce the μ-alkenylidene species with activation of the acyl C=O double bond and elimination of an α-hydrogen.
