1004325-01-2Relevant academic research and scientific papers
Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry
Conway, Ben,Hevia, Eva,Garcia-Alvarez, Joaquin,Graham, David V.,Kennedy, Alan R.,Mulvey, Robert E.
, p. 5241 - 5243 (2007)
Lithium TMP-aluminate iBu3Al(TMP)Li undergoes dismutation in THF solution to precipitate the tetraalkylaluminate [{Li·(THF)4}+{Al(iBu)4} -], but reacts kinetically as a TMP base towards N,N- diisopropylbenzamide to afford the crystalline ortho-aluminated species [(THF)3·Li{O(=C)N(iPr)2(C 6H4)}Al(iBu)3] and TMPH. The Royal Society of Chemistry.
