100446-71-7Relevant academic research and scientific papers
Co2(CO)8-Catalyzed Ring-Opening Carbonylation of Cyclic Ethers Using N-Silylamines
Watanabe, Yoshihisa,Nishiyama, Kazuhiro,Zhang, Kunsan,Okuda, Fumio,Kondo, Teruyuki,Tsuji, Yasushi
, p. 879 - 882 (1994)
Co2(CO)8-catalyzed ring-opening carbonylation of oxiranes and oxetane smoothly proceeds with high regioselectivity under 1 atm of carbon monoxide at room temperature to give the corresponding β- and γ-siloxy amides in high yields, respectively. 1R2>+- is thought to be an active catalyst species and directs the high regioselectivity of the carbonylation.
Cobalt Catalysed Ring-opening Carbonylation of Cyclic Ethers using N-(Trimethylsilyl)amines
Tsuji, Yasushi,Kobayashi, Masanobu,Okuda, Fumio,Watanabe, Yoshihisa
, p. 1253 - 1254 (1989)
N-(Trimethylsilyl)amines direct ring-opening carbonylation of a variety of cyclic ethers such as oxiranes (1-3), oxetane (4), tetrahydrofuran (5), and 1,3-dioxolane (6) in the presence of a catalytic amount of Co2(CO)8 under carbon monoxide pressure to gi
