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Benzene, 1-(ethenyloxy)-3-methyl-, also known as 1-(2-propenyloxy)-3-methylbenzene or 3-methyl-1-allyloxybenzene, is an organic compound with the chemical formula C10H12O. It is a colorless liquid with a molecular weight of 148.20 g/mol. Benzene, 1-(ethenyloxy)-3-methyl- is characterized by a benzene ring with a methyl group at the 3-position and an allyl ether group at the 1-position. It is used as an intermediate in the synthesis of various chemicals, particularly in the production of pharmaceuticals and agrochemicals. Due to its reactivity, it is important to handle Benzene, 1-(ethenyloxy)-3-methyl- with care, following proper safety protocols.

1005-40-9

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1005-40-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1005-40-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,0 and 5 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1005-40:
(6*1)+(5*0)+(4*0)+(3*5)+(2*4)+(1*0)=29
29 % 10 = 9
So 1005-40-9 is a valid CAS Registry Number.

1005-40-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-ethenoxy-3-methylbenzene

1.2 Other means of identification

Product number -
Other names m-vinyloxytoluene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1005-40-9 SDS

1005-40-9Relevant academic research and scientific papers

Polymer-supported β-bromoethyl selenide: An efficient reagent for the synthesis of aryl vinyl ethers

Sheng, Shou-Ri,Liu, Xiao-Ling,Wang, Xing-Cong,Xin, Qin,Song, Cai-Sheng

, p. 2833 - 2836 (2004)

A simple and efficient procedure for the solid-phase synthesis of aryl vinyl ethers using polymer-supported β-bromoethyl selenide with traceless linker strategy is described.

Solid-Phase synthesis of aryl vinyl ethers based on polystyrenesupported aβ-phenylselenoethanol

Zhang, Jia-Li,Sheng, Shou-Ri,Liub, Xue,Lin, Shu-Ying

, p. 287 - 289 (2009)

A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported β-phenylselenoethanol with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide has been developed. The ad

Solid-phase organic synthesis of aryl vinyl ethers using sulfone-linking strategy

Yu, Lamei,Tang, Ni,Sheng, Shouri,Chen, Rubing,Liu, Xiaoling,Cai, Mingzhong

, p. 1027 - 1030 (2012)

A novel facile solid-phase organic synthesis of aryl vinyl ethers by reaction of polystyrene-supported 2-phenylsulfonylethanol with phenols under Mitsunobu conditions and subsequent elimination reaction with DBU has been developed. The advantages of this method include straightforward operation, good yield and high purity of the products. Alternatively, a typical example of Suzuki coupling reaction on-resin was further applied to prepare 4-phenylphenyl vinyl ether for extending this method.

Nucleophilic addition to acetylenes in superbasic catalytic systems: XVIII. Vinylation of phenols and naphthols with acetylene

Trofimov,Oparina,Kolyvanov,Vysotskaya,Gusarova

, p. 188 - 194 (2015/04/14)

Phenols and naphthols react with acetylene in a superbasic system KOH-DMSO forming the corresponding aryl vinyl ethers in up to 80% yields.

Three-component reaction between vinyl ethers, secondary phosphines, and elemental selenium: One-pot synthesis of 1-(Alkoxy)ethyl and 1-(Aryloxy)ethyl phosphinodiselenoates

Gusarova, Nina K.,Artemev, Alexander V.,Oparina, Ludmila A.,Kolyvanov, Nikita A.,Malysheva, Svetlana F.,Vysotskaya, Oksana V.,Trofimov, Boris A.

experimental part, p. 431 - 438 (2012/03/11)

A family of previously unknown phosphinodiselenoic esters containing a selenoacetal moiety, R2(=Se)SeCH(Me)OR1 (R1, R2=alkyl, aryl, etc.), were synthesized by means of a three-component reaction between the elem

β-Phenylselenoethanol, an efficient reagent for the one-pot synthesis of aryl vinyl ethers

Fu, Gui-Yun,Yu, La-Mei,Mao, Xue-Chun,Wu, Dan

experimental part, p. 595 - 597 (2009/10/15)

β-Phenylselenoethanol was treated with phenols under Mitsunobu conditions and subsequent oxidation-elimination with 30% hydrogen peroxide furnished aryl vinyl ethers with good yields (85-90%) in a one-pot, two-step transformation.

Indenylacetic acid compounds

-

, (2008/06/13)

4, 5, 6 or 7 Aryl substituted indenyl acetic acids and pharmaceutically acceptable salts, amides and esters thereof. The 4, 5, 6 or 7 aryl substituted indenyl acetic acids have anti-inflammatory, anti-pyretic and analgesic activity. The invention also includes methods for the preparation of these compounds, pharmaceutical compositions and methods of treating inflammation by administering these particular compounds to patients.

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