100520-05-6

Basic information

• Product Name: 2,2-bis(ethylthio)-1-phenylethanol
• Synonyms: 2,2-bis(ethylthio)-1-phenylethanol
• CAS NO: 100520-05-6
• Molecular Weight: 242.406
• Mol File: 100520-05-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-bis(ethylthio)-1-phenylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-bis(ethylthio)-1-phenylethanol(100520-05-6)
• EPA Substance Registry System: 2,2-bis(ethylthio)-1-phenylethanol(100520-05-6)

Safety Data

• Hazardous Substances Data: 100520-05-6(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 75-08-1 ethanethiol 
• 84543-50-0 2,2-bis(ethylthio)-1-phenylethan-1-one 

Downstream Products

• 34025-29-1 mandelaldehyde 

Relevant articles and documents

Mn(III)-based reactions of alkenes and alkynes with thiols. An approach toward substituted 2,3-dihydro-1,4-oxathiins and simple route to (E)-vinyl sulfides

The first example using manganese(III) acetate in the reaction of 1,1- diarylethenes with α-mercaptoketones was examined. A mixture of the ethenes and α-mercaptoketones was treated with manganese(III) acetate in acetic acid, affording cycloaddition products in moderate yields, together with substituted products. The reaction may involve the formation of a carbonation and subsequent cyclization to give the substituted 2,3-dihydro-1,4-oxathiin 3. A similar reaction with thioglycolic acid gave 1,4-oxathiolan-2-one 7. While thiyl radicals easily formed by manganese(III) oxidation with ethanethiol or benzenethiol reacted with alkynes to give preferentially (E)- vinyl sulfides 10 in quantitative yields.