1005213-71-7Relevant academic research and scientific papers
Hydrolysis of osmium and ruthenium carbyne complexes
Chen, Jiangxi,Sung, Herman Ho-Yung,Williams, Ian Duncan,Jia, Guochen
, p. 6159 - 6165 (2011)
Hydrolysis reactions of MCl3(≡CCH=C(ArCl) 2)(PPh3)2 (M = Ru, Os) were investigated. Treatment of OsCl3(≡CCH=C(o,o′-C6H 3Cl2)2)(PPh3)2 with water produced the six-membered metallacycle OsCl(κC,κCl-CH=C(o,o′- C6H3Cl2)2)(CO)(PPh3) 2. Reactions of MCl3(≡CCH=C(o-C6H 4Cl)2)(PPh3)2 (M = Ru, Os) produced the related six-membered metallacycles MCl(κC,κCl-CH=C(o-C 6H4Cl)2)(CO)(PPh3)2.
