100571-31-1

Upstream product

• 100571-53-7 6-(benzyloxy)hex-2-yn-1-ol 
• 100-39-0 benzyl bromide 
• 57618-47-0 5-benzyloxy-1-pentyne 
• 68-12-2 N,N-dimethyl-formamide 
• 5390-04-5 pent-1-yn-5-ol 

Downstream Products

• 100571-33-3 erythro-4-vinyl-1,10-bis(benzyloxy)-6-decyn-5-ol 
• 100571-33-3 threo-4-vinyl-1,10-bis(benzyloxy)-6-decyn-5-ol 
• 1257518-30-1 4-(5-benzyloxypent-1-ynyl)oxetan-2-one 
• 100571-39-9 cis-(E)-7-methyl-4-<3-(benzyloxy)propyl>-10-(benzyloxy)-5-hydroxy-6-decenoic acid δ-lactone 
• 100571-35-5 erythro-(Z)-4-vinyl-7-iodo-1,10-bis(benzyloxy)-6-decen-5-ol 
• 100571-36-6 erythro-(E)-7-methyl-4-vinyl-1,10-bis(benzyloxy)-6-decen-5-ol 

Relevant academic research and scientific papers

A palladium nanoparticle-nanomicelle combination for the stereo-selective semihydrogenation of alkynes in water at room temperature

The addition of NaBH4 to Pd(OAc) 2 in water containing nanomicelles leads to the generation of H2 and Pd nanoparticles. Subsequent reduction of disubstituted alkynes affords Z-alkenes in high yields. These reactions are general, take place in water at ambient temperatures, and offer recycling of the aqueous reaction mixture along with low overall E Factors.

The Synthesis of Cembranolide Precursors via Addition of Allylstannanes to Conjugated Aldehydes

The Lewis acid promoted addition of functionalized allylstannanes A9, C10, and C11 to a variety of conjugated aldehydes was examined as a possible route to acyclic precursors of macrocyclic diterpenoids.Additions to crotonaldehyde proceeded as expected, g