100702-66-7Relevant academic research and scientific papers
Synthesis and Acylation of Allylic Mercuric Iodides: A Convenient Synthesis of Allylic Ketones
Larock, Richard C.,Lu, Yong-de
, p. 2846 - 2850 (1993)
Allylic mercuric iodides are readily prepared by the reaction of mercury(0) and allylic iodides.They undergo efficient acylation with allylic rearrangement upon reaction with acyl chlorides and aluminium chloride to provide a convenient synthesis of allylic ketones.Artemisia ketone is prepared in two steps by this approach.
SYNTHESIS OF ALLYLIC KETONES VIA ACYLATION OF ALLYLIC MERCURIALS
Larock, Richard C.,Lu, Yong-de
, p. 6761 - 6764 (1988)
Allylic mercurials, readily available from allylic halides and mercury(0), react with acyl chlorides and AlCl3 under mild reaction conditions to afford high yields of allylic ketones.
Regiospecific Synthesis of β, γ-Unsaturated Ketones from Allylic Alcohols. Claisen Rearrangement of α-Allyloxy Ketone Enol Derivatives
Kachinsky, Joseph L. C.,Salomon, Robert G.
, p. 1393 - 1401 (2007/10/02)
β,γ-Unsaturated ketones are prepared with regiospecific C-C bond formation at the former γ-position of primary, secondary, or tertiary allylic alcohol precursors by a process involving sigmatropic Claisen rearrangement of intermediate α-allyloxy ket
