1007224-95-4Relevant academic research and scientific papers
Synthesis of optically active (+)-canangone, its 6-epimer, and determination of absolute configuration
Koripelly, Girish,Saak, Wolfgang,Christoffers, Jens
, p. 5840 - 5846 (2008/04/13)
The first synthesis of canangone and its 6-epimer is reported. The products are obtained in optically active form by an asymmetric Robinson annulation. The relative and absolute configuration of the natural product is established for the first time. Wiley
Enantioselective Michael-type reaction of chiral linear α,α-disubstituted secondary enamines
Felk,Revial,Viossat,Lemoine,Pfau
, p. 1459 - 1462 (2007/10/02)
The enantioselective Michael-type reaction of chiral 2-substituted cyclic imines, reacting as their secondary enamine tautomers, has been extended to a linear ketamine possessing an oxo group on one of the substituents. A single secondary enamine tautomer
